{"id":"W2145399341","doi":"10.1002/anie.201210012","title":"Assembly of a <i>cyclo</i>‐Tetrastibinotetraphosphonium Tetracation by Reductive Elimination","year":2013,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Synthesis and characterization of novel inorganic/organometallic compounds","field":"Chemistry","cited_by":42,"is_retracted":false,"has_abstract":true,"ca_institutions":"Dalhousie University; University of Alberta; University of Victoria","funders":"","keywords":"Reductive elimination; Chemistry; Computer science; Service (business); Redox; Combinatorial chemistry; World Wide Web; Library science; Organic chemistry; Catalysis; Business","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00009032456,0.0002069143,0.0001204879,0.0001411705,0.0001421633,0.000267125,0.0002358552,0.0002396946,0.00162486],"category_scores_gemma":[0.0001122439,0.0001977546,0.0001719428,0.0001282309,0.0001221683,0.0001718651,0.0002107956,0.0003296696,0.0009171274],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002585159,"about_ca_system_score_gemma":0.0001863416,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005758171,"about_ca_topic_score_gemma":0.000834549,"domain_scores_codex":[0.9999166,0.000006354967,0.000007365313,0.00002832124,0.00001833932,0.00002297865],"domain_scores_gemma":[0.9999264,0.000005597079,0.00001703127,0.00001444443,0.00001639528,0.00001997043],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004185422,0.00001266652,0.00008994769,0.0000155262,0.000004711964,0.00002614079,0.00001719467,0.0001119211,0.9972344,0.0002764234,0.0001057258,0.002063479],"study_design_scores_gemma":[0.00001215166,0.0001376837,0.0004690958,0.000001766173,0.000006737785,0.000066908,0.000008627387,0.00106125,0.9942786,0.00004869277,0.003902736,0.000005769495],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9770833,0.0002477721,0.01357801,0.0001057379,0.00009487987,0.00009847502,0.0002919202,0.0005181162,0.007981755],"genre_scores_gemma":[0.9828731,0.0001492993,0.01054267,0.00006233867,0.000007287333,0.00005655609,0.0003778509,0.00006177509,0.005869146],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00162486,"threshold_uncertainty_score":0.005435646,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008499201607692462,"score_gpt":0.2202479031871391,"score_spread":0.2117487015794467,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}