{"id":"W2145443414","doi":"10.1002/cctc.201300723","title":"Oxidative Additions of Aryl Halides to Palladium Proceed through the Monoligated Complex","year":2013,"lang":"en","type":"article","venue":"ChemCatChem","topic":"Catalytic Cross-Coupling Reactions","field":"Chemistry","cited_by":100,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Victoria","funders":"Natural Sciences and Engineering Research Council of Canada; Institut Català d'Investigació Química; British Columbia Knowledge Development Fund; University of Victoria","keywords":"Iodobenzene; Palladium; Chemistry; Oxidative addition; Bromobenzene; Fluorobenzene; Aryl; Photochemistry; Reactivity (psychology); Catalysis; Adduct; Halide; Reactive intermediate; Molecule; Organic chemistry; Benzene","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.00005225506,0.0002275006,0.0002747129,0.00002917461,0.0001936045,0.00008452462,0.0004419899,0.0001155804,0.003713284],"category_scores_gemma":[0.0003356866,0.0001830284,0.000127724,0.0003987453,0.000285307,0.0001748034,0.0001387317,0.0002369534,0.0005791664],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001255559,"about_ca_system_score_gemma":0.00009119177,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0009096175,"about_ca_topic_score_gemma":0.00003343129,"domain_scores_codex":[0.9987158,4.28676e-7,0.0003795862,0.0003410947,0.0002310232,0.000332054],"domain_scores_gemma":[0.9983305,0.0002878146,0.0001856901,0.0006815673,0.0003965709,0.0001178526],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000008830726,0.0001320025,0.0001257376,0.00006262124,0.00008585483,5.680649e-7,0.002888672,0.00001908731,0.9653801,0.0001426221,0.03090318,0.0002507126],"study_design_scores_gemma":[0.0002723181,0.0000093211,0.00111026,0.00006131244,0.00004510268,0.000008945839,0.003959034,0.0002143867,0.9873979,0.001427552,0.005285512,0.0002083562],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.988225,0.00002557676,0.00004961042,0.002981361,0.00004163229,0.0002990372,0.0001992198,0.0001762641,0.008002285],"genre_scores_gemma":[0.9965692,0.000006938208,0.0003800529,0.0002037857,0.0001383632,0.000346586,0.0003348986,0.00004080978,0.001979428],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02561767,"threshold_uncertainty_score":0.9971974,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03408666644939145,"score_gpt":0.2822770907337177,"score_spread":0.2481904242843262,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}