{"id":"W2146016058","doi":"10.1002/anie.201205744","title":"Accessing the Coordination Chemistry of Phosphorus(I) Zwitterions","year":2012,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":49,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Windsor; Western University","funders":"","keywords":"Steric effects; Ligand (biochemistry); Chemistry; Phosphorus; Boron; Coordination complex; Atom (system on chip); Ion; Computational chemistry; Combinatorial chemistry; Crystallography; Computer science; Stereochemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001073394,0.0004361419,0.0001932294,0.0001339811,0.0002703345,0.0006848635,0.0005853831,0.0004154334,0.01421301],"category_scores_gemma":[0.0001783782,0.0001606153,0.0001370885,0.0001559804,0.0001585219,0.0005947344,0.0006681819,0.0003668026,0.00273116],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003517094,"about_ca_system_score_gemma":0.0001664352,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006639099,"about_ca_topic_score_gemma":0.0007990017,"domain_scores_codex":[0.9999496,0.000006280155,0.000002277829,0.00001376264,0.00001174134,0.00001646761],"domain_scores_gemma":[0.9999731,0.000008903528,0.000005119873,0.000004338571,0.00000308697,0.000005505387],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000470076,0.00007337001,0.0006035253,0.0009039357,0.00003682186,0.0009914036,0.0004554435,0.004726507,0.8831078,0.03136019,0.0116463,0.06562453],"study_design_scores_gemma":[0.0002249323,0.0004304052,0.0009878424,0.00006541784,0.00004807338,0.0004796565,0.0003658835,0.01858707,0.8908339,0.01751855,0.07037508,0.00008312063],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9341241,0.002555872,0.01048949,0.0008719186,0.0001085118,0.00004345712,0.000565537,0.001003383,0.05023778],"genre_scores_gemma":[0.9839389,0.001904261,0.005561166,0.0001461683,0.00002893881,0.00003722406,0.0003879806,0.0001304596,0.007864716],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01421301,"threshold_uncertainty_score":0.04754722,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01881904063556405,"score_gpt":0.2562307465188214,"score_spread":0.2374117058832574,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}