{"id":"W2146063721","doi":"10.1002/anie.200353126","title":"Luminescent 2D Macrocyclic Networks Based on Starburst Molecules: [{Ag(CF<sub>3</sub>SO<sub>3</sub>)}<sub>1.5</sub>(tdapb)] and [{Ag(NO<sub>3</sub>)}<sub>3</sub>(tdapb)]","year":2004,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Metal-Organic Frameworks: Synthesis and Applications","field":"Chemistry","cited_by":154,"is_retracted":false,"has_abstract":true,"ca_institutions":"Steacie Institute for Molecular Sciences; Queen's University","funders":"","keywords":"Trifluoromethanesulfonate; Luminescence; Molecule; Ligand (biochemistry); Honeycomb; Salt (chemistry); Ion; Chemistry; Combinatorial chemistry; Photochemistry; Materials science; Physical chemistry; Optoelectronics; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00005027607,0.0002245598,0.000160192,0.0001446202,0.0001596237,0.000380652,0.0002424644,0.0002138447,0.001341225],"category_scores_gemma":[0.0001276199,0.000149268,0.0001120674,0.00008917756,0.000288415,0.000220525,0.0002987999,0.0002260493,0.0002889823],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002723919,"about_ca_system_score_gemma":0.0001443011,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006225197,"about_ca_topic_score_gemma":0.001845173,"domain_scores_codex":[0.9999503,0.000006587585,0.000002582529,0.00001703601,0.000009446265,0.00001405315],"domain_scores_gemma":[0.9999011,0.00001890116,0.00002912073,0.00001044395,0.000008458057,0.00003201683],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001556167,0.00002789115,0.0002900219,0.0000879424,0.00001206559,0.0001265932,0.00006993055,0.001957336,0.991702,0.001458416,0.0001988911,0.003913302],"study_design_scores_gemma":[0.00006057664,0.0004575254,0.003013184,0.00001378693,0.00002011799,0.0002621336,0.00006308521,0.007965839,0.9791015,0.0003931741,0.008621324,0.00002772332],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9901841,0.000485015,0.005289741,0.00005769933,0.00002530102,0.00002677062,0.0001525061,0.0002132917,0.00356564],"genre_scores_gemma":[0.9916649,0.0002323977,0.00625191,0.00003153622,0.000004067706,0.0000410046,0.0001216709,0.00002552252,0.001626985],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001341225,"threshold_uncertainty_score":0.004486859,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009029742183206221,"score_gpt":0.2213325538374381,"score_spread":0.2123028116542319,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}