{"id":"W2146063721","doi":"10.1002/anie.200353126","title":"Luminescent 2D Macrocyclic Networks Based on Starburst Molecules: [{Ag(CF<sub>3</sub>SO<sub>3</sub>)}<sub>1.5</sub>(tdapb)] and [{Ag(NO<sub>3</sub>)}<sub>3</sub>(tdapb)]","year":2004,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Metal-Organic Frameworks: Synthesis and Applications","field":"Chemistry","cited_by":154,"is_retracted":false,"has_abstract":true,"ca_institutions":"Steacie Institute for Molecular Sciences; Queen's University","funders":"","keywords":"Trifluoromethanesulfonate; Luminescence; Molecule; Ligand (biochemistry); Honeycomb; Salt (chemistry); Ion; Chemistry; Combinatorial chemistry; Photochemistry; Materials science; Physical chemistry; Optoelectronics; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","scholarly_communication","research_integrity","insufficient_payload"],"consensus_categories":["metaepi_narrow","research_integrity"],"category_scores_codex":[0.001136218,0.00254457,0.001901461,0.0008644545,0.001269383,0.001077167,0.001921096,0.002200747,0.0003578806],"category_scores_gemma":[0.001319457,0.002816898,0.00130343,0.001440217,0.001069079,0.001249791,0.0006804233,0.002968889,0.0007781115],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.002365764,"about_ca_system_score_gemma":0.0006915425,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00006080032,"about_ca_topic_score_gemma":0.0002253964,"domain_scores_codex":[0.9874446,0.0002326563,0.00295575,0.003659811,0.003237377,0.002469824],"domain_scores_gemma":[0.9912924,0.001301228,0.002050587,0.002410706,0.001507393,0.001437724],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0005868569,0.001910153,0.000216202,0.0004439668,0.0007223345,0.0001786888,0.0002643982,0.002271324,0.9554659,0.0006648113,0.02348849,0.01378687],"study_design_scores_gemma":[0.004487605,0.0002276962,0.001375175,0.002260719,0.0006385799,0.0001789259,0.0002738462,0.005153965,0.974737,0.001836924,0.006088866,0.00274071],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9629557,0.001010597,0.02132021,0.004283766,0.00299435,0.001530395,0.001834104,0.000990302,0.003080631],"genre_scores_gemma":[0.9727419,0.005094393,0.0005284586,0.003461227,0.008586455,0.001363606,0.007544041,0.0006278472,0.0000520499],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02079175,"threshold_uncertainty_score":0.9999999,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009029742183206221,"score_gpt":0.2213325538374381,"score_spread":0.2123028116542319,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}