{"id":"W2146064363","doi":"10.1002/anie.200806048","title":"Selective CF Bond Activation of Tetrafluorobenzenes by Nickel(0) with a Nitrogen Donor Analogous to N‐Heterocyclic Carbenes","year":2009,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"N-Heterocyclic Carbenes in Organic and Inorganic Chemistry","field":"Chemistry","cited_by":92,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Windsor","funders":"","keywords":"Nickel; Chemistry; Nitrogen; HEXA; Ligand (biochemistry); Oxidative addition; Transition metal; Medicinal chemistry; Stereochemistry; Photochemistry; Combinatorial chemistry; Catalysis; Organic chemistry; Biochemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.00005855264,0.0003330223,0.0003276922,0.0001027817,0.00008602663,0.00005244955,0.0004106829,0.0002277788,0.000598776],"category_scores_gemma":[0.0001089805,0.0003233133,0.0001292288,0.0002507855,0.00006873252,0.0003297782,0.00005857983,0.0002475657,0.00001040648],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004407092,"about_ca_system_score_gemma":0.00005579845,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001165142,"about_ca_topic_score_gemma":0.00001490397,"domain_scores_codex":[0.9980932,0.000007078329,0.0004626683,0.0005377302,0.0005860457,0.0003132477],"domain_scores_gemma":[0.9987842,0.00008267535,0.0003046361,0.0003301123,0.0003445457,0.0001538156],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000242354,0.0002142293,0.001062643,0.00004446684,0.0001654775,0.000003442695,0.0002119557,0.00001223965,0.9802563,0.00003597897,0.01634935,0.001401542],"study_design_scores_gemma":[0.0009179093,0.0001161631,0.0003120535,0.0001662184,0.00005373776,0.00004861682,0.0002210056,0.00001242042,0.9937091,0.0005318467,0.00355842,0.0003525295],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9763063,0.0001215922,0.001221309,0.0007858644,0.000199603,0.0001273113,0.000290685,0.0001348052,0.02081254],"genre_scores_gemma":[0.9966593,0.0000611214,0.0003392827,0.000410052,0.0009415044,0.00003748092,0.0009450355,0.0000397472,0.0005664294],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02035305,"threshold_uncertainty_score":0.9999219,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006037652435181166,"score_gpt":0.2287491967282168,"score_spread":0.2227115442930357,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}