{"id":"W2146211834","doi":"10.1007/s11144-011-0352-x","title":"Kinetics at the nanoscale: formation and aqueous oxidation of copper nanoparticles","year":2011,"lang":"en","type":"article","venue":"Reaction Kinetics Mechanisms and Catalysis","topic":"Gold and Silver Nanoparticles Synthesis and Applications","field":"Materials Science","cited_by":18,"is_retracted":false,"has_abstract":false,"ca_institutions":"Concordia University","funders":"","keywords":"Sodium borohydride; Copper; Nanoparticle; Aqueous solution; Surface plasmon resonance; Inorganic chemistry; Chemistry; Materials science; Kinetics; Chemical engineering; Nanotechnology; Physical chemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001507344,0.00009059795,0.0001236016,0.000036173,0.0001467925,0.00002998606,0.00006670383,0.0000469744,0.0000891669],"category_scores_gemma":[0.00001764595,0.00006336497,0.00003147651,0.0001108326,0.00008938079,0.0001190936,0.00005798702,0.00002603627,0.00001812499],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00001637276,"about_ca_system_score_gemma":0.000003099337,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0000749236,"about_ca_topic_score_gemma":0.00006912313,"domain_scores_codex":[0.9992864,0.0000314318,0.0002499369,0.0001639128,0.000146901,0.0001214108],"domain_scores_gemma":[0.9994833,0.00003625596,0.0001569242,0.0002048562,0.00006379142,0.0000549049],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001308839,0.00007275838,0.00001909625,0.00001075575,0.000005399741,1.830022e-7,0.000396875,0.000002261995,0.9870158,0.003584852,0.00003552528,0.008843377],"study_design_scores_gemma":[0.000116277,0.00008404662,0.001419388,0.000008335883,0.0001003525,0.00001596361,0.0003367866,0.0001956176,0.9955299,0.001461822,0.0006514402,0.00008006288],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9979039,0.0002006339,0.001242882,0.0001838167,0.00004247588,0.000123685,0.00001112689,0.00002083746,0.0002706835],"genre_scores_gemma":[0.9982392,0.0002455177,0.001322469,0.00003995894,0.00001176021,0.00002503434,0.00001179121,0.000007527632,0.00009672078],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.008763314,"threshold_uncertainty_score":0.2583948,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0187116675547363,"score_gpt":0.2087266006860492,"score_spread":0.1900149331313129,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}