{"id":"W2146862057","doi":"10.1039/c2dt32917d","title":"A mechanistic analysis of the tetrasilyl-substituted trimetallaallenes, >EEE< (E = C, Si, Ge, Sn, and Pb)","year":2013,"lang":"en","type":"article","venue":"Dalton Transactions","topic":"Synthesis and characterization of novel inorganic/organometallic compounds","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"National Science Council; Ministère de l'Économie, de la Science et de l'Innovation - Québec","keywords":"Reactivity (psychology); Chemistry; Steric effects; Allene; Density functional theory; Intramolecular force; Kinetic energy; Electronic effect; Computational chemistry; Atom (system on chip); Chemical reaction; Carbon group; Group (periodic table); Stereochemistry; Organic chemistry; Catalysis","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001523225,0.0004663721,0.0004402492,0.0003683348,0.0003962466,0.0003736278,0.0006630218,0.0005114497,0.005293666],"category_scores_gemma":[0.0001780759,0.000194083,0.0006162314,0.0002630336,0.0003306687,0.0005932698,0.0002833172,0.0005572851,0.0003134111],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000457059,"about_ca_system_score_gemma":0.0004255021,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001545371,"about_ca_topic_score_gemma":0.002345989,"domain_scores_codex":[0.9999617,0.000005325821,0.000001140604,0.000007617843,0.00001102478,0.00001315304],"domain_scores_gemma":[0.9999394,0.00002480818,0.00001164036,0.000007575423,0.000009301061,0.000007193968],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"simulation_or_modeling","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003625988,0.0004143752,0.004700098,0.001206578,0.0001445026,0.001451846,0.0002702281,0.6633489,0.1722768,0.128936,0.001991462,0.02489666],"study_design_scores_gemma":[0.00003915433,0.0003407103,0.002982423,0.00003292474,0.00006005876,0.0002937185,0.0001996492,0.941696,0.03626401,0.01529584,0.002762328,0.00003332607],"study_design_candidate":"bench_or_experimental","study_design_consensus":null,"genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9601282,0.001297125,0.01349703,0.0002719396,0.00003800175,0.00004357595,0.0006561935,0.00008685805,0.02398106],"genre_scores_gemma":[0.9944312,0.0006245851,0.002572475,0.00003296374,0.000005075481,0.00004738189,0.0003056503,0.00001434586,0.001966183],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.005293666,"threshold_uncertainty_score":0.01770908,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01257824714567086,"score_gpt":0.208937749708951,"score_spread":0.1963595025632801,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}