{"id":"W2147239754","doi":"10.1139/v02-102","title":"Vibrational spectroscopic studies of aqueous solutions of <i>tert</i>-butyl alcohol and <i>tert</i>-butylamine","year":2002,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Spectroscopy and Quantum Chemical Studies","field":"Physics and Astronomy","cited_by":8,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"University of Auckland; New Zealand Government","keywords":"Chemistry; Aqueous solution; Solvent; Raman spectroscopy; Butylamine; Infrared spectroscopy; Mole fraction; Solvent effects; Infrared; Spectral line; Analytical Chemistry (journal); Physical chemistry; Organic chemistry; Amine gas treating","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002270098,0.0003303908,0.0001633399,0.0001806424,0.0001518583,0.0001800678,0.0002748221,0.0002491387,0.001147463],"category_scores_gemma":[0.0004306564,0.0001185277,0.0001282076,0.000275941,0.0002487392,0.0002134304,0.0001395523,0.0004534272,0.0001633993],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001594675,"about_ca_system_score_gemma":0.0001589743,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007871868,"about_ca_topic_score_gemma":0.0008093251,"domain_scores_codex":[0.999867,0.00002246196,0.000008726162,0.00002478282,0.00005402747,0.00002302942],"domain_scores_gemma":[0.9996626,0.000131456,0.00008854534,0.00001032546,0.00007801909,0.00002901644],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003701936,0.00001023878,0.00006742656,0.00002547821,0.000002622252,0.00001171278,0.0000278281,0.00005734425,0.9992008,0.00002319305,0.000007131617,0.0005291834],"study_design_scores_gemma":[0.000006742835,0.000284949,0.001391652,0.000005598916,0.00001372735,0.00004034374,0.0000554048,0.000773099,0.9969853,0.00002497319,0.0004133551,0.000004892202],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9920988,0.0009960068,0.005130711,0.00006156886,0.00003003211,0.00003116125,0.0001401393,0.00003753306,0.001474109],"genre_scores_gemma":[0.9894112,0.001421914,0.006802571,0.00005060545,0.0000145677,0.00005884258,0.0003042217,0.00002298128,0.001913088],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001147463,"threshold_uncertainty_score":0.003838599,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02721581252408178,"score_gpt":0.2504438110975132,"score_spread":0.2232279985734314,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}