{"id":"W2147407521","doi":"10.1002/anie.201410033","title":"The Phosphinoboration Reaction","year":2014,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Organophosphorus compounds synthesis","field":"Chemistry","cited_by":75,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of New Brunswick; Mount Allison University","funders":"Engineering and Physical Sciences Research Council; Natural Sciences and Engineering Research Council of Canada; Mount Allison University; Newcastle University; University of New Brunswick","keywords":"Regioselectivity; Aldimine; Reactivity (psychology); Chemistry; Double bond; Single bond; Catalysis; Stereochemistry; Medicinal chemistry; Combinatorial chemistry; Organic chemistry; Group (periodic table)","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001981772,0.0006497883,0.0002292228,0.0003061841,0.0005234845,0.0003630202,0.0004178066,0.000414234,0.006219783],"category_scores_gemma":[0.0001891955,0.0002809546,0.0002046632,0.0002020597,0.0003190208,0.0006567474,0.0006998085,0.001010501,0.003510129],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003287065,"about_ca_system_score_gemma":0.0004966275,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004526939,"about_ca_topic_score_gemma":0.0007549551,"domain_scores_codex":[0.9998075,0.00002046437,0.00001237055,0.00006771438,0.00003514638,0.00005674932],"domain_scores_gemma":[0.9999608,0.000005334595,0.000007217453,0.000007812304,0.000008697371,0.00001015264],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003370839,0.0001052044,0.0004231129,0.001007651,0.00006164514,0.0009078897,0.0002849983,0.0007760806,0.8950014,0.01737294,0.005442712,0.07827931],"study_design_scores_gemma":[0.00004249015,0.0004012341,0.0003568514,0.00002912209,0.00003098757,0.001232391,0.000032789,0.0003665251,0.8871255,0.001734079,0.1086188,0.00002928633],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.5263307,0.03579241,0.2288304,0.003958503,0.002635239,0.001143228,0.003580146,0.004129712,0.1935996],"genre_scores_gemma":[0.9287829,0.008655211,0.02474865,0.0006771705,0.0000665558,0.0002184869,0.001185808,0.00015339,0.03551174],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.006219783,"threshold_uncertainty_score":0.02080721,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008036183728112652,"score_gpt":0.2220814623839514,"score_spread":0.2140452786558387,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}