{"id":"W2147407521","doi":"10.1002/anie.201410033","title":"The Phosphinoboration Reaction","year":2014,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Organophosphorus compounds synthesis","field":"Chemistry","cited_by":75,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of New Brunswick; Mount Allison University","funders":"Engineering and Physical Sciences Research Council; Natural Sciences and Engineering Research Council of Canada; Mount Allison University; Newcastle University; University of New Brunswick","keywords":"Regioselectivity; Aldimine; Reactivity (psychology); Chemistry; Double bond; Single bond; Catalysis; Stereochemistry; Medicinal chemistry; Combinatorial chemistry; Organic chemistry; Group (periodic table)","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002339932,0.0001336022,0.00008495211,0.00003017214,0.0002662673,0.0001461317,0.0002952056,0.0001013421,0.0006431332],"category_scores_gemma":[0.000444812,0.0001105709,0.00007448027,0.00007832835,0.00006716832,0.0003095592,0.00004349706,0.0001634545,0.0001836981],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002296998,"about_ca_system_score_gemma":0.0000230661,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00004336771,"about_ca_topic_score_gemma":0.0000207969,"domain_scores_codex":[0.9989163,0.00001092279,0.0002378434,0.000235386,0.0004318734,0.0001676856],"domain_scores_gemma":[0.9990222,0.0002870235,0.0001693525,0.0002702484,0.000200636,0.00005054011],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005529026,0.00004705591,0.0003156652,0.000008446548,0.00004679949,9.340968e-7,0.00005750479,0.000003834276,0.961286,0.003142169,0.02146629,0.01357001],"study_design_scores_gemma":[0.0001715655,0.000005607978,0.0003274902,0.00001841924,0.00001071492,0.000007274003,0.00005071555,0.0002395208,0.7226979,0.002779987,0.2735953,0.0000955603],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"other","genre_gemma":"empirical","genre_scores_codex":[0.2958617,0.0003182369,0.009842318,0.01971158,0.009379694,0.0001870011,0.0000999242,0.0008850252,0.6637145],"genre_scores_gemma":[0.9933367,0.0001477858,0.0001416738,0.0001653129,0.002871259,0.00004674305,0.0002813619,0.00002432442,0.002984846],"genre_candidate":"empirical","genre_consensus":null,"teacher_disagreement_score":0.697475,"threshold_uncertainty_score":0.7041857,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008036183728112652,"score_gpt":0.2220814623839514,"score_spread":0.2140452786558387,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}