{"id":"W2147639456","doi":"10.1139/v03-034","title":"Synthesis and in vitro reactivity of <i>cis</i>-dichloro-(pyridin-2-ylcarboxaldimine)platinum(II) complexes with DNA","year":2003,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Metal complexes synthesis and properties","field":"Medicine","cited_by":27,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Chemistry; Platinum; Stereochemistry; Monoclinic crystal system; Reactivity (psychology); Nuclease; DNA; Cisplatin; Crystallography; Crystal structure; Organic chemistry; Biochemistry","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0004361451,0.0001745479,0.000622339,0.0001181626,0.00007011763,0.00001783092,0.0001054622,0.00008515284,0.0002270857],"category_scores_gemma":[0.0006911964,0.0001325883,0.00008202663,0.0001519323,0.0002355295,0.00008704498,0.000008792409,0.0002741273,4.111228e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00009090339,"about_ca_system_score_gemma":0.0009147263,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0008887088,"about_ca_topic_score_gemma":0.0009272068,"domain_scores_codex":[0.9988919,0.00005094237,0.0004305631,0.0001481487,0.0002150017,0.0002633953],"domain_scores_gemma":[0.9987163,0.0001681534,0.000280083,0.0002127358,0.0001541274,0.000468577],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0004268466,0.00003836416,0.006915853,0.0002184458,0.00007129124,0.0001314847,0.0002116943,0.000002848282,0.9908051,0.000007627148,0.0002240494,0.0009464168],"study_design_scores_gemma":[0.0005846564,0.0001040039,0.003955497,0.0004496328,0.00008851993,0.00113775,0.000333949,0.000008137932,0.9875224,0.00005406444,0.005624979,0.0001363638],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9863626,0.00167537,0.000006506797,0.0003459224,0.00002843231,0.00007006674,0.00002083757,0.000002781924,0.01148751],"genre_scores_gemma":[0.9989347,0.00003133875,0.0006576568,0.0000902986,0.00005408945,0.000002586358,0.000001605753,0.0000204903,0.0002071788],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01257219,"threshold_uncertainty_score":0.5406796,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02121662403406068,"score_gpt":0.2110469270540312,"score_spread":0.1898303030199706,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}