{"id":"W2148030748","doi":"10.1002/anie.201404120","title":"Development of CN Coupling Using Mechanochemistry: Catalytic Coupling of Arylsulfonamides and Carbodiimides","year":2014,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Catalytic Cross-Coupling Reactions","field":"Chemistry","cited_by":127,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University; Centre in Green Chemistry and Catalysis","funders":"","keywords":"Mechanochemistry; Coupling (piping); Catalysis; Component (thermodynamics); Molecule; Chemistry; Combinatorial chemistry; Computational chemistry; Organic chemistry; Materials science; Thermodynamics; Metallurgy; Physics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000452348,0.0005408703,0.0002374921,0.0002151157,0.0001402958,0.0002126005,0.0004140814,0.0002990182,0.0009133313],"category_scores_gemma":[0.0003137782,0.0002099844,0.0002108575,0.0001396028,0.0003279583,0.0003512216,0.0003492874,0.0004670166,0.000322183],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004147755,"about_ca_system_score_gemma":0.0005718261,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007544193,"about_ca_topic_score_gemma":0.00148637,"domain_scores_codex":[0.9997655,0.00002770434,0.00001768134,0.00006459231,0.00008632236,0.00003838335],"domain_scores_gemma":[0.9998585,0.00003185412,0.00002999767,0.00001807857,0.00003835966,0.00002312154],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002330993,0.00002653377,0.0001459336,0.0001262996,0.000005704996,0.0001161519,0.00002365291,0.000253806,0.9902941,0.001180799,0.00007190901,0.007731826],"study_design_scores_gemma":[0.000009705165,0.0001609985,0.0004189304,0.000005850326,0.000005436275,0.0002723588,0.000008270409,0.0008350863,0.9936773,0.00008354929,0.004515756,0.000006789456],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8267986,0.00636768,0.1435468,0.0004462183,0.0004249766,0.0004187274,0.0002670618,0.000449307,0.02128056],"genre_scores_gemma":[0.9367713,0.003929254,0.05474178,0.0001271631,0.0000386612,0.0001163784,0.0002249908,0.00003380274,0.004016768],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0009133313,"threshold_uncertainty_score":0.003055394,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02220656820697579,"score_gpt":0.2725699180628922,"score_spread":0.2503633498559164,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}