{"id":"W2148097316","doi":"10.1007/s10953-010-9510-4","title":"Experimental Determination of Third Derivative of the Gibbs Free Energy, G II: Differential Pressure Perturbation Calorimetry","year":2010,"lang":"en","type":"article","venue":"Journal of Solution Chemistry","topic":"Thermodynamic properties of mixtures","field":"Chemical Engineering","cited_by":9,"is_retracted":false,"has_abstract":false,"ca_institutions":"University of British Columbia","funders":"","keywords":"Chemistry; Gibbs free energy; Thermodynamics; Aqueous solution; Mole fraction; Heat capacity; Calorimetry; Enthalpy; Second derivative; Derivative (finance); Entropy of mixing; Entropy (arrow of time); Standard molar entropy; Thermal; Third order; Physical chemistry; Mathematical analysis; Physics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0006901405,0.0008683789,0.0004058855,0.0006101613,0.0006537751,0.0005434743,0.0009318552,0.0008767825,0.003382983],"category_scores_gemma":[0.00123076,0.0003832435,0.0002329228,0.0007514929,0.00126685,0.0005497126,0.0004937186,0.002102093,0.0008732308],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005039842,"about_ca_system_score_gemma":0.0005199723,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007561561,"about_ca_topic_score_gemma":0.0008638605,"domain_scores_codex":[0.9992408,0.0001086313,0.00003094523,0.0001972628,0.0003017604,0.00012064],"domain_scores_gemma":[0.9994838,0.0002211243,0.00004314892,0.0001081091,0.000107465,0.00003625417],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006870565,0.00003718493,0.0004742598,0.00005237948,0.000007674144,0.000019666,0.00003316294,0.0002297931,0.9958877,0.0008047245,0.0002814241,0.002103223],"study_design_scores_gemma":[0.000002643316,0.00002409737,0.0006993745,0.000001925984,0.000003341694,0.00002658352,0.000007912169,0.0008670828,0.9976919,0.00009841207,0.0005724455,0.000004356113],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8775628,0.001810784,0.102929,0.0006335083,0.0003066721,0.0001214419,0.003281419,0.00123453,0.01211989],"genre_scores_gemma":[0.9741097,0.0007900764,0.02113958,0.0001760926,0.00003104404,0.0001594221,0.001296133,0.000192368,0.002105553],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003382983,"threshold_uncertainty_score":0.01131719,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005648140732524899,"score_gpt":0.2081580439856743,"score_spread":0.2025099032531494,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}