{"id":"W2148132766","doi":"10.1039/c0dt00542h","title":"The first unpaired electron placed inside a C3-symmetry P-chirogenic cluster","year":2010,"lang":"en","type":"article","venue":"Dalton Transactions","topic":"Magnetism in coordination complexes","field":"Materials Science","cited_by":22,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Lethbridge; Université de Sherbrooke","funders":"","keywords":"Unpaired electron; Electron paramagnetic resonance; Crystallography; Chemistry; Intramolecular force; Delocalized electron; Hyperfine structure; Steric effects; Cluster (spacecraft); Enantiomer; Paramagnetism; Tetragonal crystal system; Radical; Stereochemistry; Nuclear magnetic resonance; Crystal structure; Atomic physics; Physics; Condensed matter physics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0004751366,0.0001860378,0.0001520747,0.0001012062,0.001212574,0.0002218786,0.0004587198,0.0001147961,0.002265617],"category_scores_gemma":[0.00006851042,0.0001482173,0.0001165337,0.0003347553,0.0001988816,0.0002507942,0.00001190388,0.000417058,0.0004399267],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00004855642,"about_ca_system_score_gemma":0.00009929631,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002690588,"about_ca_topic_score_gemma":0.01210193,"domain_scores_codex":[0.9984647,0.00008943801,0.0003351219,0.0003488487,0.0003156296,0.000446264],"domain_scores_gemma":[0.9986379,0.0004822041,0.0001006348,0.0005821663,0.00008931253,0.0001078265],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"not_applicable","study_design_scores_codex":[0.0001594979,0.0002091994,0.0001950193,0.00003642361,0.00004267096,0.000003345823,0.0006693048,0.000328165,0.9725572,0.006362254,0.008929673,0.01050724],"study_design_scores_gemma":[0.001110835,0.0001439188,0.003965315,0.00001123793,0.00007511485,0.00008600181,0.0001095204,0.002665743,0.4912165,0.002219791,0.4979599,0.0004361652],"study_design_candidate":"bench_or_experimental","study_design_consensus":null,"genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9565767,0.0001305399,0.02396805,0.01020949,0.003105399,0.0006030747,0.00007352862,0.0004549891,0.004878238],"genre_scores_gemma":[0.9952504,0.00003745836,0.001470211,0.0003522814,0.0001435601,0.0001521023,0.000008284681,0.00003061961,0.002555078],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.4890302,"threshold_uncertainty_score":0.9986464,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01066001536210846,"score_gpt":0.2417730897114308,"score_spread":0.2311130743493223,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}