{"id":"W2148176937","doi":"10.1139/v05-067","title":"Palladium(II) complexes of bis(phosphine)monooxide and bis(phosphine)monosulphide ligands bearing <i>o</i>-<i>N</i>,<i>N</i>-dimethylanilinyl substituents","year":2005,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":3,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Chemistry; Phosphine; Palladium; Medicinal chemistry; Phosphine oxide; Metal; Stereochemistry; Catalysis; Organic chemistry","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001073626,0.0003618226,0.000265789,0.0001418032,0.0001153998,0.0003122021,0.0005145975,0.0002955936,0.00123583],"category_scores_gemma":[0.0001839418,0.0001861769,0.000120491,0.0001367736,0.0001816424,0.0001869636,0.0003508506,0.0003149324,0.0002668147],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004279742,"about_ca_system_score_gemma":0.00014062,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004531887,"about_ca_topic_score_gemma":0.0007407897,"domain_scores_codex":[0.9998701,0.00002521994,0.000009832776,0.00002181763,0.00004175987,0.0000314057],"domain_scores_gemma":[0.9999428,0.000008096674,0.00001403492,0.00000407706,0.000007516037,0.00002342093],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0005693755,0.00004785831,0.0001871935,0.0003772509,0.00002585818,0.0001297771,0.00005638737,0.0009587613,0.9914875,0.001544431,0.0006399454,0.003975628],"study_design_scores_gemma":[0.00009241735,0.0004130687,0.0004860895,0.000008762195,0.00002301183,0.0001601146,0.00002917541,0.00151912,0.9889477,0.0001367536,0.008175069,0.0000085861],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9821937,0.003392786,0.00484773,0.0001783275,0.00009874548,0.00007612884,0.0002059733,0.0002693112,0.008737302],"genre_scores_gemma":[0.9897023,0.00136607,0.002758374,0.00007387565,0.00001760077,0.00004935359,0.0003330959,0.00002203519,0.00567723],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00123583,"threshold_uncertainty_score":0.004134297,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00861384017567817,"score_gpt":0.2084248849271393,"score_spread":0.1998110447514612,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}