{"id":"W2148314425","doi":"10.1021/jp806689j","title":"FTIR Analysis of Dimethyl Ether Decomposition Products Following Charge Transfer Ionization with Ar<sup>+</sup> under Matrix Isolation Conditions","year":2008,"lang":"en","type":"article","venue":"The Journal of Physical Chemistry A","topic":"Advanced Chemical Physics Studies","field":"Physics and Astronomy","cited_by":16,"is_retracted":false,"has_abstract":true,"ca_institutions":"Trent University","funders":"","keywords":"Chemistry; Dimethyl ether; Fragmentation (computing); Ionization; Electron ionization; Ether; Matrix isolation; Photochemistry; Analytical Chemistry (journal); Chemical ionization; Argon; Infrared; Ion; Methanol; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000276185,0.0005485289,0.0002490572,0.0003992258,0.0003194633,0.0002636709,0.0004562976,0.0002927634,0.004764253],"category_scores_gemma":[0.0004190804,0.0001719695,0.000247731,0.0006229565,0.000179101,0.0004573135,0.0001766058,0.0005209414,0.0008024421],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001811143,"about_ca_system_score_gemma":0.0001847435,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005329357,"about_ca_topic_score_gemma":0.0009563135,"domain_scores_codex":[0.9998041,0.0000107839,0.00000787941,0.00004065917,0.0001114594,0.0000251913],"domain_scores_gemma":[0.9997768,0.00004789036,0.00004935424,0.00001561483,0.0000900724,0.00002032464],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004310198,0.000006832634,0.0001815097,0.00002663595,0.000003117647,0.00002249047,0.00001363567,0.0000215357,0.9980035,0.0000267283,0.00003421044,0.001616727],"study_design_scores_gemma":[0.000004049537,0.00009405713,0.007272991,0.000004623847,0.00001595339,0.0002027225,0.00004978368,0.0005002056,0.9894571,0.00003504193,0.002357357,0.000006277634],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9751456,0.001771087,0.01368339,0.00009264224,0.00005647941,0.00005172581,0.002522199,0.0002212298,0.006455658],"genre_scores_gemma":[0.9533809,0.003200582,0.02566447,0.000146943,0.00003057064,0.00009991116,0.006036581,0.0001960813,0.0112439],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.004764253,"threshold_uncertainty_score":0.01593804,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009348080264313285,"score_gpt":0.2706355216642791,"score_spread":0.2612874413999658,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}