{"id":"W2148517814","doi":"10.1139/v00-189","title":"Synthesis, X-ray crystal structure, and solid-state <sup>13</sup>C NMR study of tris(9-crown-3)triphenylene","year":2001,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Molecular Sensors and Ion Detection","field":"Chemistry","cited_by":9,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Triphenylene; Chemistry; Crown ether; Crystallography; Monoclinic crystal system; Crystal structure; Triclinic crystal system; Ether; Trimer; 18-Crown-6; Stereochemistry; Molecule; Dimer; Organic chemistry","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00005781952,0.0001203229,0.00008867115,0.00009319426,0.0001152946,0.0001441174,0.0001379765,0.0001230265,0.001401875],"category_scores_gemma":[0.0001150891,0.00007457649,0.0000584221,0.0001378335,0.0001119134,0.0001190997,0.00004944221,0.0001752055,0.0003338795],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002397175,"about_ca_system_score_gemma":0.0001687934,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0008714258,"about_ca_topic_score_gemma":0.001819687,"domain_scores_codex":[0.9999672,0.000002768945,0.000002188176,0.000005439369,0.00001530339,0.000007219261],"domain_scores_gemma":[0.9999604,0.000006745964,0.00001221054,0.000003268821,0.000008164532,0.000009258732],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005786395,0.00001157493,0.0000953726,0.00002818031,0.000002822632,0.0000568646,0.00001407718,0.0001537973,0.9979193,0.0000915831,0.00006737553,0.001501346],"study_design_scores_gemma":[0.00001372211,0.0001388349,0.001568882,0.000002322551,0.000009281004,0.0001582171,0.00001369395,0.0003862062,0.9952666,0.00002764999,0.002410898,0.000003734027],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.993181,0.000844562,0.002375642,0.00007170928,0.00001512618,0.00001769384,0.0007616165,0.00005644857,0.002676142],"genre_scores_gemma":[0.988354,0.0008112438,0.0062126,0.00002730193,0.000005726192,0.00001282714,0.001701513,0.00003081791,0.002843871],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001401875,"threshold_uncertainty_score":0.004689753,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007079621438445785,"score_gpt":0.2050513123603311,"score_spread":0.1979716909218853,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}