{"id":"W2148735818","doi":"10.1002/0471264180.os061.28","title":"Preparation of Thiol Esters: S‐ <i>tert</i> ‐Butyl Cyclohexanecarbothioate and <i>S‐tert</i> ‐Butyl 3α,7α,12α‐Trihydroxy‐5β‐cholane‐24‐thioate","year":2003,"lang":"en","type":"other","venue":"Organic Syntheses","topic":"Chemical Synthesis and Reactions","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"","keywords":"Chemistry; Thiol; Chloride; Organic chemistry; Thallium; Product (mathematics); Medicinal chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","research_integrity","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0002532318,0.0009857656,0.001349507,0.0002224724,0.0001639601,0.000162525,0.0005926074,0.00135112,0.01408285],"category_scores_gemma":[0.0006170848,0.0008697129,0.0003568823,0.0002662227,0.0003530227,0.0001688941,0.0001915529,0.0007467803,0.0002310156],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001539736,"about_ca_system_score_gemma":0.0001427075,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003660105,"about_ca_topic_score_gemma":0.0001519022,"domain_scores_codex":[0.9963406,0.0001216049,0.0009494074,0.001218914,0.0006379143,0.0007315486],"domain_scores_gemma":[0.9965025,0.0008119019,0.0009656828,0.00131953,0.00007823706,0.0003221135],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"not_applicable","study_design_scores_codex":[0.00006690362,0.0003763136,0.0002711016,0.001050516,0.0005406972,0.00002928047,0.0002528227,8.191619e-7,0.9069666,0.00004842017,0.08747453,0.002922023],"study_design_scores_gemma":[0.0003595176,0.00003455245,0.000006761182,0.001535851,0.0003985306,0.0001394264,0.0001180802,0.00001058815,0.4922883,0.00006094223,0.5042581,0.0007893911],"study_design_candidate":"bench_or_experimental","study_design_consensus":null,"genre_codex":"other","genre_gemma":"other","genre_scores_codex":[0.02989785,0.006553112,0.00006219393,0.0004292805,0.001083426,0.000613649,0.000654688,0.0007905982,0.9599152],"genre_scores_gemma":[0.4794882,0.007230889,0.0004159971,0.0004651664,0.001279963,0.0001445413,0.000209496,0.001467075,0.5092987],"genre_candidate":"other","genre_consensus":"other","teacher_disagreement_score":0.4506165,"threshold_uncertainty_score":0.9999453,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0110346165412179,"score_gpt":0.2388296183057675,"score_spread":0.2277950017645496,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}