{"id":"W2148735818","doi":"10.1002/0471264180.os061.28","title":"Preparation of Thiol Esters: S‐ <i>tert</i> ‐Butyl Cyclohexanecarbothioate and <i>S‐tert</i> ‐Butyl 3α,7α,12α‐Trihydroxy‐5β‐cholane‐24‐thioate","year":2003,"lang":"en","type":"other","venue":"Organic Syntheses","topic":"Chemical Synthesis and Reactions","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"","keywords":"Chemistry; Thiol; Chloride; Organic chemistry; Thallium; Product (mathematics); Medicinal chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002384953,0.001094796,0.0003306536,0.0004330895,0.0002651019,0.0001935593,0.0003673949,0.0002336388,0.007861038],"category_scores_gemma":[0.0001927566,0.0002543904,0.0003463585,0.0003440408,0.0001762559,0.000258125,0.0003068451,0.0003605436,0.003644766],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000313424,"about_ca_system_score_gemma":0.0004662906,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0009322802,"about_ca_topic_score_gemma":0.001564775,"domain_scores_codex":[0.9998631,0.00001473438,0.00001077554,0.00002323473,0.00004391661,0.00004430882],"domain_scores_gemma":[0.9998713,0.00001597965,0.00002074465,0.00002159652,0.00003248831,0.00003788866],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001027046,0.00001958446,0.00005836794,0.0001185092,0.000008241886,0.0001214485,0.00002996692,0.0001397927,0.9949785,0.0002272379,0.0003233284,0.003872309],"study_design_scores_gemma":[0.00001951263,0.00009227807,0.0001826641,0.000003152175,0.000006877364,0.00007201086,0.000008366413,0.00009768589,0.9961164,0.00001818719,0.003379566,0.000003372528],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"methods","genre_scores_codex":[0.8943596,0.003479762,0.04265969,0.0003693906,0.0003397062,0.0006921076,0.003160046,0.001412973,0.05352688],"genre_scores_gemma":[0.8588073,0.004847409,0.02362774,0.0001331588,0.00007454945,0.0004515407,0.005281598,0.0006140674,0.1061627],"genre_candidate":"methods","genre_consensus":null,"teacher_disagreement_score":0.007861038,"threshold_uncertainty_score":0.02629781,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0110346165412179,"score_gpt":0.2388296183057675,"score_spread":0.2277950017645496,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}