{"id":"W2148830958","doi":"10.1139/v05-035","title":"Recent advances in cyclohydrocarbonylation reactions","year":2005,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Asymmetric Synthesis and Catalysis","field":"Chemistry","cited_by":29,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Foundation for the National Institutes of Health; National Science Foundation","keywords":"Chemistry; Regioselectivity; Hydroformylation; Intramolecular force; Nucleophile; Catalysis; Rhodium; Combinatorial chemistry; Cascade reaction; Organic chemistry; Bicyclic molecule; Carbonylation; Organic reaction; Organic synthesis; Carbon monoxide","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00115355,0.001119481,0.0007739692,0.001421211,0.0003635,0.0007867623,0.0008794051,0.0008499855,0.004226055],"category_scores_gemma":[0.0008539733,0.0006277146,0.0005673168,0.001652079,0.0005113858,0.001818485,0.0009042861,0.001743558,0.00298015],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0008595605,"about_ca_system_score_gemma":0.0005533229,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007151074,"about_ca_topic_score_gemma":0.0007710831,"domain_scores_codex":[0.9993398,0.00008733336,0.00006891935,0.0002052969,0.0002124796,0.00008602859],"domain_scores_gemma":[0.9995782,0.0001548856,0.00006605685,0.00003765677,0.0001282328,0.00003505791],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"design_other","study_design_gemma":"not_applicable","study_design_scores_codex":[0.0003694664,0.0002504383,0.0005222365,0.01410528,0.0001808135,0.0008097301,0.0004010845,0.002692647,0.1635409,0.01931268,0.01239864,0.7854161],"study_design_scores_gemma":[0.00004163453,0.0006260699,0.0007532755,0.0003830081,0.0002059545,0.002689349,0.00009871556,0.001281951,0.1628956,0.002743678,0.8281888,0.00009187536],"study_design_candidate":"not_applicable","study_design_consensus":null,"genre_codex":"review","genre_gemma":"review","genre_scores_codex":[0.01264113,0.943096,0.01339142,0.0009509528,0.0007203761,0.00005768549,0.000114981,0.0001653919,0.02886206],"genre_scores_gemma":[0.07723728,0.9041299,0.007702645,0.0008387478,0.001094373,0.0000598201,0.0003633486,0.00005870499,0.0085152],"genre_candidate":"review","genre_consensus":"review","teacher_disagreement_score":0.004226055,"threshold_uncertainty_score":0.01413757,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007076357228707381,"score_gpt":0.2135385345081062,"score_spread":0.2064621772793988,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}