{"id":"W2148947737","doi":"10.1002/anie.200700345","title":"A Formally Zwitterionic Ruthenium Catalyst Precursor for the Transfer Hydrogenation of Ketones that Does Not Feature an Ancillary Ligand NH Functionality","year":2007,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":104,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Saskatchewan; University of Alberta; Dalhousie University","funders":"","keywords":"Transfer hydrogenation; Ruthenium; Ligand (biochemistry); Aryl; Catalysis; Alkyl; Transfer (computing); Chemistry; Combinatorial chemistry; Range (aeronautics); Computer science; Medicinal chemistry; Organic chemistry; Materials science; Operating system; Biochemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001227017,0.0003491841,0.0001726996,0.0001456523,0.00009842699,0.0002388606,0.0005377731,0.0003075691,0.001764771],"category_scores_gemma":[0.0001826107,0.0001451786,0.0001023305,0.0001592903,0.0001555264,0.0003925749,0.0001956691,0.000539521,0.0006905],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002370564,"about_ca_system_score_gemma":0.0001986348,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003272272,"about_ca_topic_score_gemma":0.000566779,"domain_scores_codex":[0.9999142,0.000008835118,0.000007729112,0.00002093329,0.00002773649,0.00002050734],"domain_scores_gemma":[0.9999244,0.000009505936,0.00002200064,0.00001670616,0.00000891465,0.00001838569],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004250493,0.00001385781,0.00004342494,0.0000523287,0.000003880139,0.0001240105,0.00001517521,0.00006567402,0.9964615,0.0005372717,0.0001126588,0.00252768],"study_design_scores_gemma":[0.00001125021,0.0001630212,0.0002707724,0.000002939742,0.000007569011,0.0003494951,0.000008436123,0.0003304727,0.9968479,0.00005260167,0.001951136,0.000004271128],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9684368,0.001099501,0.01905125,0.0002046996,0.00008056447,0.00008263633,0.0004656218,0.0004389182,0.01014005],"genre_scores_gemma":[0.9922659,0.0003399734,0.004622009,0.00001690445,0.000007137781,0.00001497637,0.0002917232,0.00003261991,0.002408776],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001764771,"threshold_uncertainty_score":0.00590378,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01841599738861525,"score_gpt":0.2579947975161798,"score_spread":0.2395788001275645,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}