{"id":"W2148970773","doi":"10.1002/chin.200144242","title":"ChemInform Abstract: Synthesis of (+)‐Juruenolide C: Use of Sequential 5‐exo‐digonal Radical Cyclization 1,5‐Intramolecular Hydrogen Transfer, and 5‐endo‐trigonal Cyclization.","year":2001,"lang":"en","type":"article","venue":"ChemInform","topic":"Radical Photochemical Reactions","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"","keywords":"Chemistry; Intramolecular force; Trigonal crystal system; Radical cyclization; Transfer (computing); Combinatorial chemistry; Stereochemistry; Crystallography; Crystal structure; Operating system; Computer science","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001521428,0.0004003116,0.000604332,0.0001439392,0.00009519279,0.00004872264,0.0003559635,0.0005251588,0.003425401],"category_scores_gemma":[0.001032415,0.0004115156,0.0003109799,0.0003863301,0.0006634457,0.0005811934,0.0000785747,0.000385424,0.000009339474],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000178632,"about_ca_system_score_gemma":0.0001984131,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001063167,"about_ca_topic_score_gemma":0.000006207873,"domain_scores_codex":[0.9970597,4.473003e-7,0.00123381,0.0004129416,0.0007840067,0.0005090766],"domain_scores_gemma":[0.998091,0.0004998646,0.0003112628,0.0004910558,0.0001957942,0.0004110259],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003024063,0.0003324556,0.0003643904,0.0005363328,0.0002526404,0.00002036771,0.0001879361,0.00002774312,0.9040727,0.0006148205,0.0008612986,0.09242693],"study_design_scores_gemma":[0.000856949,0.00001774089,0.0002555835,0.0001926737,0.0001829512,0.0001361781,0.000052961,0.0004119457,0.9813799,0.0002509227,0.01588779,0.0003744717],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.7835932,0.0001710265,0.00008396796,0.00008768411,0.00004734641,0.0002707604,0.0002588522,0.0001240488,0.2153631],"genre_scores_gemma":[0.9973487,0.0004562294,0.000179656,0.0000629188,0.0001280755,0.00006788497,0.0003819056,0.00005725551,0.001317371],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.2140457,"threshold_uncertainty_score":0.9998336,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01758525166043019,"score_gpt":0.238523760363878,"score_spread":0.2209385087034478,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}