{"id":"W2149060111","doi":"10.1002/adsc.200404228","title":"One‐Pot Carbon Monoxide‐Free Hydroformylation of Internal Olefins to Terminal Aldehydes","year":2005,"lang":"en","type":"article","venue":"Advanced Synthesis & Catalysis","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":62,"is_retracted":false,"has_abstract":true,"ca_institutions":"Queen's University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Hydroformylation; Chemistry; Hydroboration; Olefin fiber; Aldehyde; Carbon monoxide; Isomerization; Catalysis; Rhodium; Organic chemistry; Terminal (telecommunication); Propene","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002544124,0.0007936255,0.0004743132,0.0002879364,0.0002257536,0.000207488,0.000500908,0.0003205402,0.002280921],"category_scores_gemma":[0.0001958658,0.0002436167,0.0003826197,0.0001878685,0.0002935897,0.000384991,0.0005501518,0.0007478333,0.001031383],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003364877,"about_ca_system_score_gemma":0.0004401329,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005920844,"about_ca_topic_score_gemma":0.001640625,"domain_scores_codex":[0.9997801,0.00002302182,0.00001572764,0.00004526096,0.00005153499,0.00008442935],"domain_scores_gemma":[0.999849,0.00002000636,0.0000290581,0.00003076535,0.0000289127,0.00004225563],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001448575,0.00005389141,0.0001285513,0.0002068438,0.00002605912,0.0001677991,0.00006096938,0.0003091436,0.9904619,0.0003410585,0.0001763844,0.007922553],"study_design_scores_gemma":[0.00002365026,0.000165659,0.0005611703,0.000006021342,0.00001479057,0.0001828393,0.000007657824,0.000197891,0.9963546,0.00003694962,0.002437658,0.00001101368],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.935389,0.002114065,0.04792432,0.0002326402,0.0001573093,0.0003147783,0.001090692,0.0005166538,0.01226038],"genre_scores_gemma":[0.9820447,0.001230362,0.009367978,0.00006719954,0.00001889116,0.00005608781,0.0007616127,0.00007314574,0.006380043],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002280921,"threshold_uncertainty_score":0.007630467,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007613640673519852,"score_gpt":0.2290550841791183,"score_spread":0.2214414435055984,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}