{"id":"W2149667117","doi":"10.1002/celc.201500166","title":"Combining Noble Metals and Enzymes for Relay Cascade Electrocatalysis of Nitrate Reduction to Ammonia at Neutral pH","year":2015,"lang":"en","type":"article","venue":"ChemElectroChem","topic":"Ammonia Synthesis and Nitrogen Reduction","field":"Chemical Engineering","cited_by":32,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"","keywords":"Nitrate; Nitrate reductase; Nitrite; Chemistry; Electrocatalyst; Inorganic chemistry; Noble metal; Ammonia; Catalysis; Electrochemistry; Combinatorial chemistry; Electrode; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0002759433,0.0002522003,0.0004598665,0.0001230404,0.00008802854,0.00002097479,0.0001285695,0.0001550335,0.000009248673],"category_scores_gemma":[0.000159002,0.0002539793,0.000150846,0.0003538479,0.00004520584,0.0001442973,0.00005346593,0.0001601953,0.000009472071],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002243747,"about_ca_system_score_gemma":0.00005254312,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00005069104,"about_ca_topic_score_gemma":0.00001012574,"domain_scores_codex":[0.9985086,0.0000183583,0.0003854573,0.0004207513,0.0001776653,0.0004891671],"domain_scores_gemma":[0.9991384,0.00006326872,0.0001482458,0.0002446195,0.000158695,0.0002467482],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002535746,0.00004720825,0.00002223832,0.00005823585,0.0001701439,4.227426e-7,0.0004661341,0.0002658237,0.9969758,0.0006216587,0.0006125198,0.0005061874],"study_design_scores_gemma":[0.0005926336,0.0001810286,0.000014637,0.0000225303,0.0001916147,0.00006774413,0.0002194996,0.001978376,0.9957415,0.0001648356,0.0005582276,0.0002674156],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9950631,0.001724891,0.002275768,0.0002401681,0.00007082659,0.0002865307,0.000006078493,0.0001023639,0.0002302728],"genre_scores_gemma":[0.9927694,0.00003064726,0.005698191,0.00001824004,0.0001805636,0.0001376544,0.00004591415,0.00005625625,0.001063094],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003422423,"threshold_uncertainty_score":0.9999912,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0224968328659635,"score_gpt":0.2500246999804163,"score_spread":0.2275278671144528,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}