{"id":"W2150016075","doi":"10.1002/anie.200906632","title":"Total Synthesis of (+)‐Isatisine A","year":2010,"lang":"de","type":"article","venue":"Angewandte Chemie International Edition","topic":"Cyclopropane Reaction Mechanisms","field":"Chemistry","cited_by":137,"is_retracted":false,"has_abstract":true,"ca_institutions":"Western University","funders":"","keywords":"Cyclopropane; Tetrahydrofuran; Total synthesis; Key (lock); Ring (chemistry); Construct (python library); Information retrieval; Computer science; Chemistry; Stereochemistry; World Wide Web; Organic chemistry; Programming language","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001689784,0.0003155505,0.0003319632,0.0001641602,0.00007655952,0.00007158172,0.0003848178,0.000441975,0.01404046],"category_scores_gemma":[0.0008403854,0.0003549211,0.0002712256,0.0001410439,0.0001607753,0.0003244391,0.0001246433,0.0006398706,0.0003993901],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002049531,"about_ca_system_score_gemma":0.0001337728,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001507445,"about_ca_topic_score_gemma":0.00002300671,"domain_scores_codex":[0.9977716,0.0000130378,0.0006262171,0.0004703545,0.0008487063,0.0002700366],"domain_scores_gemma":[0.9979309,0.0002743833,0.0005610875,0.0004384583,0.0006500414,0.0001451546],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001122607,0.0002722142,0.0002091363,0.0002306698,0.0002883828,0.00001768361,0.0002679357,0.000003261574,0.9829559,0.0007447434,0.004851563,0.01004625],"study_design_scores_gemma":[0.0005793242,0.00002412545,0.0003416763,0.0002380046,0.0002012116,0.00007193768,0.0003303789,0.00009948394,0.9630141,0.0005035255,0.03428824,0.000307952],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.7662885,0.001112893,0.003261734,0.004051474,0.04644377,0.0005200234,0.004208505,0.0004071834,0.173706],"genre_scores_gemma":[0.9852893,0.0002743781,0.001469305,0.00004988691,0.01007729,0.00006854425,0.001091297,0.00005918781,0.001620852],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.2190008,"threshold_uncertainty_score":0.9998903,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008798553855718521,"score_gpt":0.2419624029906555,"score_spread":0.233163849134937,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}