{"id":"W2150290013","doi":"10.1002/anie.200351376","title":"Reductive Dimerization of Tethered Pyrenes: Implications for the Reduction of Polcyclic Aromatic Hydrocarbons","year":2003,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Coordination Chemistry and Organometallics","field":"Chemistry","cited_by":14,"is_retracted":false,"has_abstract":true,"ca_institutions":"Memorial University of Newfoundland","funders":"","keywords":"Pyrene; Reduction (mathematics); Chemistry; Lithium (medication); Lithium metal; Photochemistry; Chemical reduction; Metal; Combinatorial chemistry; Organic chemistry; Physical chemistry; Electrochemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001600715,0.0001254373,0.0001548696,0.00006018769,0.0000902632,0.00001393052,0.0002082728,0.0001004296,0.0002305885],"category_scores_gemma":[0.0006452854,0.0001136534,0.0001387009,0.000202182,0.0001375909,0.0001400517,0.00001503524,0.00008100548,0.000001120672],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00008414185,"about_ca_system_score_gemma":0.00005947347,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001214134,"about_ca_topic_score_gemma":0.000001478934,"domain_scores_codex":[0.9990675,0.00001196904,0.0004169562,0.0002041699,0.0001929546,0.0001064422],"domain_scores_gemma":[0.9987919,0.0002913904,0.0004580797,0.0002536588,0.0001722173,0.0000327283],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002609233,0.0001246162,0.0001716449,0.0000598627,0.0001389151,2.375703e-8,0.0001888905,0.00008271646,0.9942881,0.003471653,0.0004942452,0.0009532694],"study_design_scores_gemma":[0.000437359,0.00001353367,0.0003618055,0.00005099901,0.00009017583,0.00001183716,0.0003767188,0.0001262977,0.9804835,0.01456028,0.003383484,0.0001040261],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.7190382,0.0006597809,0.1978305,0.007982133,0.002492057,0.0008466752,0.0008272231,0.0002108028,0.07011261],"genre_scores_gemma":[0.9975843,0.00007477262,0.0004935694,0.00001708983,0.0004342825,0.0001457341,0.0006215831,0.00001903055,0.0006096468],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.278546,"threshold_uncertainty_score":0.4634653,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02004440740775744,"score_gpt":0.2712951292191726,"score_spread":0.2512507218114152,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}