{"id":"W2150421674","doi":"10.1039/c2py20065a","title":"Copper mediated controlled radical polymerization of methyl acrylate in the presence of ascorbic acid in a continuous tubular reactor","year":2012,"lang":"en","type":"article","venue":"Polymer Chemistry","topic":"Advanced Polymer Synthesis and Characterization","field":"Chemistry","cited_by":41,"is_retracted":false,"has_abstract":true,"ca_institutions":"Queen's University","funders":"","keywords":"Polymerization; Ascorbic acid; Copper; Methyl acrylate; Chemistry; Radical polymerization; Polymer; Polymer chemistry; Chain transfer; Copolymer; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003394558,0.0002630849,0.0006816271,0.00005983587,0.00002360896,0.00001108389,0.0003993179,0.00026461,0.0007093131],"category_scores_gemma":[0.0004727441,0.0002083757,0.0001362436,0.0003421674,0.0002041352,0.0002144674,0.00005614634,0.0002853844,0.000002963191],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00003545871,"about_ca_system_score_gemma":0.00006818063,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00008428455,"about_ca_topic_score_gemma":0.000002357883,"domain_scores_codex":[0.9979054,0.0001006163,0.0008689039,0.000263653,0.0004192599,0.0004422148],"domain_scores_gemma":[0.9983719,0.0004604016,0.00054329,0.000487346,0.00004039753,0.0000966688],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003806949,0.0003941026,0.02719491,0.0001709413,0.00004668873,0.000003711978,0.001122988,6.92939e-7,0.9695272,0.00002804693,0.000007665116,0.001122396],"study_design_scores_gemma":[0.002463572,0.000008335704,0.002016105,0.0001541303,0.00005000412,0.000008553441,0.0004427671,0.00009155621,0.9944777,0.000006170999,0.00008551381,0.0001955598],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9891261,0.008198261,0.00005807061,0.0001681892,0.0000595213,0.0001489981,0.00006675065,0.00002331108,0.002150806],"genre_scores_gemma":[0.9991789,0.0001684139,0.00002794521,0.000052356,0.000139705,0.00008704209,0.0001400864,0.00003270483,0.0001727718],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0251788,"threshold_uncertainty_score":0.8497313,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008709671252793554,"score_gpt":0.2352329399401623,"score_spread":0.2265232686873687,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}