{"id":"W2150724478","doi":"10.1021/jo049626o","title":"Syn−Anti Isomerization of Aldols by Enolization","year":2004,"lang":"en","type":"article","venue":"The Journal of Organic Chemistry","topic":"Synthetic Organic Chemistry Methods","field":"Chemistry","cited_by":33,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Saskatchewan","funders":"","keywords":"Chemistry; Isomerization; Aldol reaction; Keto–enol tautomerism; Cyclohexanone; Regioselectivity; Adduct; Medicinal chemistry; Organic chemistry; Catalysis; Tautomer","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0006258697,0.0002338165,0.000415735,0.00001965141,0.00007771653,0.00002041145,0.0007464339,0.000220053,0.00546841],"category_scores_gemma":[0.0009153901,0.0001844178,0.0001360003,0.0003164699,0.0001763622,0.0001083879,0.00009320673,0.00040728,0.000007512852],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002231731,"about_ca_system_score_gemma":0.0003064928,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0000050798,"about_ca_topic_score_gemma":1.901694e-7,"domain_scores_codex":[0.9981311,0.00003250792,0.000889699,0.00015646,0.0005485136,0.000241733],"domain_scores_gemma":[0.9976744,0.0002131458,0.001178962,0.0005441945,0.0002694812,0.0001198077],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003870834,0.0001414709,0.0001218321,0.0002213633,0.00009893322,0.000003996688,0.0003871373,0.00006866045,0.9980515,0.000004397,0.000303255,0.0005587963],"study_design_scores_gemma":[0.001023379,0.00001447075,0.00001874782,0.0002047192,0.0001831714,0.0007541142,0.000641384,0.000009411728,0.9958,0.0003591112,0.0008182161,0.0001733207],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9826479,0.0009031936,0.01230698,0.0006699633,0.0001004465,0.00003833521,0.00002088329,0.00003317411,0.003279116],"genre_scores_gemma":[0.9975476,0.0004368337,0.001086269,0.0000313246,0.0003215881,6.73541e-7,0.00001354374,0.00005732519,0.0005049049],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01489963,"threshold_uncertainty_score":0.9954407,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00781380758696302,"score_gpt":0.2372166066351287,"score_spread":0.2294027990481657,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}