{"id":"W2150752189","doi":"10.1002/anie.201505378","title":"Pushing the Limits of Neutral Organic Electron Donors: A Tetra(iminophosphorano)‐Substituted Bispyridinylidene","year":2015,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Catalytic C–H Functionalization Methods","field":"Chemistry","cited_by":102,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of New Brunswick","funders":"Natural Sciences and Engineering Research Council of Canada; Harrison McCain Foundation; Engineering and Physical Sciences Research Council; New Brunswick Innovation Foundation","keywords":"Dication; Chemistry; Redox; Saturated calomel electrode; Cyclic voltammetry; Pyridinium; Photochemistry; Tetra; Deprotonation; Aryl; Electron donor; Halide; Inorganic chemistry; Medicinal chemistry; Ion; Electrochemistry; Electrode; Organic chemistry; Alkyl; Working electrode; Physical chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0004562038,0.0002150843,0.0002066867,0.0001074521,0.00008462251,0.00008469378,0.0004614705,0.0001603449,0.001410636],"category_scores_gemma":[0.001067652,0.000188085,0.0001350638,0.0003499753,0.0001248449,0.0004163549,0.00007098543,0.0002847407,0.00003793959],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004114972,"about_ca_system_score_gemma":0.0002358412,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001681754,"about_ca_topic_score_gemma":0.00006770773,"domain_scores_codex":[0.9982512,0.00002280223,0.0004854998,0.0003393524,0.0006626928,0.0002384452],"domain_scores_gemma":[0.9982358,0.0002728828,0.0003287065,0.0003271969,0.0007132354,0.0001221331],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001891921,0.0001428885,0.0009572406,0.00004438726,0.000161569,0.000006699097,0.0004837402,0.0003156211,0.9775828,0.001762199,0.01806365,0.0002900485],"study_design_scores_gemma":[0.0008788665,0.00001927653,0.0003701001,0.00007392726,0.00006105404,0.00006393146,0.0002946448,0.0002624099,0.9815335,0.00224508,0.01400835,0.0001888627],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9582126,0.0004628831,0.0172241,0.003605088,0.003347378,0.0001856909,0.000203767,0.0002229228,0.01653561],"genre_scores_gemma":[0.9944642,0.00009884372,0.0004575693,0.0002111918,0.002133294,0.00005002154,0.001433768,0.00003854886,0.001112554],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.03625165,"threshold_uncertainty_score":0.9995022,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.04085108410296748,"score_gpt":0.2964741694816163,"score_spread":0.2556230853786488,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}