{"id":"W2150926018","doi":"10.1002/ange.201311103","title":"A Biomimetic Catalytic Aerobic Functionalization of Phenols","year":2014,"lang":"en","type":"article","venue":"Angewandte Chemie","topic":"Oxidative Organic Chemistry Reactions","field":"Chemistry","cited_by":50,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University","funders":"","keywords":"Phenols; Catalysis; Chemistry; Surface modification; Combinatorial chemistry; Aromaticity; Organic chemistry; Molecule","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.00008570447,0.0001613015,0.0002065168,0.00003639657,0.0000565078,0.00001405072,0.0001620173,0.0001166144,0.003002605],"category_scores_gemma":[0.0002312513,0.0001656455,0.00008834995,0.000235641,0.0001063192,0.00006088974,0.00004975733,0.0001039502,0.00009058986],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00009951231,"about_ca_system_score_gemma":0.00005037618,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00002352026,"about_ca_topic_score_gemma":0.000003924132,"domain_scores_codex":[0.9990792,0.000005911156,0.0002611082,0.0002703035,0.0001988124,0.0001846789],"domain_scores_gemma":[0.9990927,0.000112838,0.0001713782,0.0004225656,0.0001191021,0.00008143359],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001029762,0.00007935548,0.0007519298,0.0001565976,0.00005086966,4.240339e-7,0.00006264831,0.000005556838,0.9970704,0.0001510119,0.001364281,0.0002966036],"study_design_scores_gemma":[0.0004827834,0.000009073351,0.0001156165,0.00004895819,0.00007070154,0.00001369158,0.00006616014,0.00004686324,0.9865203,0.0003070706,0.01215749,0.0001613026],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8542945,0.0001485129,0.0007378481,0.0001658269,0.00009021591,0.0000558111,0.00003589268,0.0001475918,0.1443238],"genre_scores_gemma":[0.9944125,0.00001006278,0.0001918397,0.00003314059,0.0002107772,0.00001555511,0.0002493602,0.00003074362,0.004846032],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1401179,"threshold_uncertainty_score":0.9979088,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01445837919021037,"score_gpt":0.2286593457143898,"score_spread":0.2142009665241794,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}