{"id":"W2151409846","doi":"10.1002/chem.201405829","title":"From Minutes to Years: Predicting Organotrifluoroborate Solvolysis Rates","year":2015,"lang":"en","type":"article","venue":"Chemistry - A European Journal","topic":"Catalytic Cross-Coupling Reactions","field":"Chemistry","cited_by":61,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Solvolysis; Logarithm; Chemistry; Medicinal chemistry; Mathematics; Organic chemistry; Hydrolysis; Mathematical analysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0005711702,0.0002845472,0.0002815935,0.0000420557,0.0001977507,0.0006006577,0.0006289177,0.00007351291,0.00166713],"category_scores_gemma":[0.001208222,0.0003012933,0.0001527795,0.0002846449,0.00008972812,0.0001947309,0.0002352914,0.0007385676,0.0007098746],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002685137,"about_ca_system_score_gemma":0.0002497078,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000032259,"about_ca_topic_score_gemma":0.000001150508,"domain_scores_codex":[0.9981041,0.000006508235,0.0005688551,0.0004442463,0.0004263781,0.0004499263],"domain_scores_gemma":[0.9978446,0.0001059454,0.0003087668,0.0005896442,0.0003215778,0.0008295056],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006204902,0.00007069256,0.002012725,0.00001869127,0.0001162214,0.0004774554,0.001439492,0.0003043394,0.9785678,1.097832e-7,0.01498046,0.001949937],"study_design_scores_gemma":[0.001690441,0.00003047765,0.0004563339,0.0002823963,0.0001751748,0.0008112259,0.003036966,0.001758327,0.9656425,0.00005876958,0.02548636,0.0005710193],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9949378,0.0002733657,0.0001921058,0.0002791638,0.000252626,0.00002898529,0.0001035116,0.0001985685,0.003733807],"genre_scores_gemma":[0.9887727,0.00001281393,0.0008199911,0.00006215154,0.003781627,0.000003003215,0.0001161365,0.0001152161,0.006316349],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01292532,"threshold_uncertainty_score":0.9999439,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02921458602004,"score_gpt":0.2634050074245337,"score_spread":0.2341904214044936,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}