{"id":"W2151966537","doi":"10.1002/anie.201408371","title":"Synthesis and Reactivity of a CAAC–Aminoborylene Adduct: A Hetero‐Allene or an Organoboron Isoelectronic with Singlet Carbenes","year":2014,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":331,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Allene; Adduct; Chemistry; Carbene; Electrophile; Trimethylsilyl; Singlet state; Reactivity (psychology); Medicinal chemistry; Molecule; Photochemistry; Alkyl; Stereochemistry; Organic chemistry; Catalysis; Physics; Excited state","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001500489,0.0002962695,0.000330753,0.00007149119,0.00007978768,0.00005486081,0.0002701918,0.0002083489,0.001709083],"category_scores_gemma":[0.0002724679,0.0002544194,0.00005788475,0.0001020294,0.0001692979,0.0004278524,0.00006683791,0.0002159447,0.000003939642],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000200328,"about_ca_system_score_gemma":0.0001115176,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000117881,"about_ca_topic_score_gemma":0.0002250535,"domain_scores_codex":[0.9984369,0.00002245567,0.0003117564,0.0005182539,0.0004317504,0.0002788607],"domain_scores_gemma":[0.998776,0.0002162892,0.0002695265,0.0003675467,0.0002269428,0.0001436899],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003758617,0.0002840053,0.00209612,0.0001788945,0.0001091744,0.000007173,0.0001879245,0.000002921709,0.9929495,0.00004275992,0.0002506236,0.00351502],"study_design_scores_gemma":[0.0008654117,0.0001384405,0.0008506874,0.000204901,0.00008544765,0.0001086942,0.0001830775,0.00008840371,0.9956916,0.00007722836,0.001391702,0.0003143865],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9957824,0.0001239151,0.0002450722,0.0004989198,0.0001314774,0.00005504235,0.0001381338,0.0001106481,0.002914398],"genre_scores_gemma":[0.9978702,0.0002334606,0.0002485654,0.0001039602,0.0009673496,0.00003769445,0.000257032,0.00005435708,0.0002273954],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003200633,"threshold_uncertainty_score":0.9999908,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01097137041172886,"score_gpt":0.2323653411576284,"score_spread":0.2213939707458995,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}