{"id":"W2151966537","doi":"10.1002/anie.201408371","title":"Synthesis and Reactivity of a CAAC–Aminoborylene Adduct: A Hetero‐Allene or an Organoboron Isoelectronic with Singlet Carbenes","year":2014,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":331,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Allene; Adduct; Chemistry; Carbene; Electrophile; Trimethylsilyl; Singlet state; Reactivity (psychology); Medicinal chemistry; Molecule; Photochemistry; Alkyl; Stereochemistry; Organic chemistry; Catalysis; Physics; Excited state","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001244275,0.000216694,0.0001277837,0.0001332441,0.0001639186,0.0001895109,0.0002309018,0.0002784326,0.001353033],"category_scores_gemma":[0.00009382692,0.0001564545,0.0001126204,0.0001870627,0.0001583032,0.0001731785,0.0001615922,0.0003068498,0.0003162388],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002346033,"about_ca_system_score_gemma":0.0001600479,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007192207,"about_ca_topic_score_gemma":0.001299249,"domain_scores_codex":[0.9999071,0.000009823954,0.000005470587,0.00002347662,0.00002645435,0.00002757659],"domain_scores_gemma":[0.9999332,0.000006081073,0.00001548501,0.00001447046,0.0000105946,0.00002008547],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006251539,0.00002261093,0.0001629046,0.00002387644,0.000008557608,0.00007939299,0.00004029697,0.0001819757,0.9978203,0.0004940145,0.00004363633,0.00105993],"study_design_scores_gemma":[0.00001098081,0.0002105141,0.0008735757,0.000002393579,0.00001055462,0.0001073729,0.0000121296,0.0002886698,0.9967111,0.0000463336,0.001719858,0.00000654296],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9958704,0.0002392817,0.001381576,0.00003126379,0.00001157132,0.00001801561,0.00009357531,0.00003222823,0.002322137],"genre_scores_gemma":[0.9965012,0.0001670561,0.00120213,0.0000125101,0.000003041329,0.000009825822,0.000106737,0.00001262624,0.001984733],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001353033,"threshold_uncertainty_score":0.004526317,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01097137041172886,"score_gpt":0.2323653411576284,"score_spread":0.2213939707458995,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}