{"id":"W2152473620","doi":"10.1021/ja909399u","title":"A Direct Comparison of Reactivity and Mechanism in the Gas Phase and in Solution","year":2010,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Advanced Chemical Physics Studies","field":"Physics and Astronomy","cited_by":70,"is_retracted":false,"has_abstract":true,"ca_institutions":"Laurentian University","funders":"Air Force Office of Scientific Research; Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Gas phase; Mechanism (biology); Reactivity (psychology); Phase (matter); Physical chemistry; Organic chemistry; Epistemology","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001801371,0.00007322511,0.0002772888,0.000006284788,0.00003205339,0.000006043218,0.0001237371,0.00001498448,0.000001151686],"category_scores_gemma":[0.0000259176,0.00004258959,0.0001047452,0.0001378436,0.0003353649,0.00005788397,0.0000811973,0.0004996092,3.288409e-8],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00001831841,"about_ca_system_score_gemma":0.00001236584,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00008024183,"about_ca_topic_score_gemma":0.00000319957,"domain_scores_codex":[0.9994649,0.00002854086,0.0002007748,0.00007397598,0.0001245542,0.0001072939],"domain_scores_gemma":[0.999261,0.000217495,0.0003843682,0.0000871373,0.00002627396,0.00002374618],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003018828,0.0002555494,0.01395394,0.000003816492,0.00002134175,8.105015e-8,0.0009026066,0.000002315069,0.9804782,0.0001648114,0.0001070947,0.004080058],"study_design_scores_gemma":[0.0009018448,0.00005141709,0.00382835,0.0000273712,0.00003431462,0.000002372778,0.002245247,0.0004365927,0.962364,0.02991248,0.0001078596,0.00008818974],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9988684,0.00002705926,0.0002290061,0.0006439045,0.00001899703,0.00004655861,0.000004256301,0.000001027593,0.0001607669],"genre_scores_gemma":[0.9989933,0.00001074914,0.000864965,0.00004334845,0.00008064743,0.000001887104,2.844115e-7,0.000003892253,8.715854e-7],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02974767,"threshold_uncertainty_score":0.2170581,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01206528969081744,"score_gpt":0.3002472883786595,"score_spread":0.2881819986878421,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}