{"id":"W2152726296","doi":"10.1002/chem.201300491","title":"Transition‐Metal‐Free One‐Pot Synthesis of Biaryls from Grignard Reagents and Substituted Cyclohexanones","year":2013,"lang":"en","type":"article","venue":"Chemistry - A European Journal","topic":"Catalytic C–H Functionalization Methods","field":"Chemistry","cited_by":36,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University","funders":"","keywords":"Aromatization; Grignard reagent; Transition metal; Chemistry; Grignard reaction; Reagent; Dehydration; Combinatorial chemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002265981,0.0005259258,0.0003698684,0.0004074618,0.000278479,0.0003113692,0.0006304414,0.0003723578,0.002262517],"category_scores_gemma":[0.0001464695,0.000259307,0.000263779,0.0003089413,0.0002041377,0.0005365001,0.0004851389,0.0008749973,0.001316871],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002765674,"about_ca_system_score_gemma":0.0003326518,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003725679,"about_ca_topic_score_gemma":0.001111483,"domain_scores_codex":[0.9998381,0.00001831793,0.00001847867,0.00002975879,0.00004620372,0.00004908767],"domain_scores_gemma":[0.9999518,0.000005375285,0.00001054134,0.000008985937,0.000006254843,0.00001709326],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001027043,0.00009070335,0.00008653934,0.0002838358,0.00002137074,0.0003298466,0.00009558973,0.0003085919,0.9783496,0.005198562,0.0005605725,0.01457215],"study_design_scores_gemma":[0.00004048398,0.0003570635,0.0004452883,0.00001634985,0.00001962083,0.0003183565,0.00001655735,0.0007686958,0.9842616,0.0005027559,0.013228,0.00002525339],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8101562,0.01283153,0.1265381,0.001116157,0.0007314377,0.0004411115,0.001403996,0.002335921,0.04444557],"genre_scores_gemma":[0.9500821,0.005139257,0.03333671,0.0001840737,0.0000543056,0.000133662,0.0006752698,0.0001421927,0.01025256],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002262517,"threshold_uncertainty_score":0.007568836,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02463864714287891,"score_gpt":0.2224748588248329,"score_spread":0.197836211681954,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}