{"id":"W2153178286","doi":"10.1021/om0607671","title":"Synthesis, Characterization, and Photocontrolled Ring-Opening Polymerization of Sila[1]ferrocenophanes with Multiple Alkyne Substituents","year":2007,"lang":"en","type":"article","venue":"Bristol Research (University of Bristol)","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":15,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Acetylide; Chemistry; Alkyne; Polymerization; Catalysis; Polymer chemistry; Polymer; Ring-opening polymerization; Monomer; Ring (chemistry); Transition metal; Medicinal chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0007164096,0.0001683838,0.0005068308,0.0004008655,0.0003656002,0.00002812372,0.0004294477,0.0001062337,0.001602559],"category_scores_gemma":[0.0003473265,0.0001928252,0.00008805479,0.0006434727,0.0005283923,0.0002745561,0.0001800658,0.0001697765,0.00000574953],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001009926,"about_ca_system_score_gemma":0.0001053738,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001457529,"about_ca_topic_score_gemma":0.0006237593,"domain_scores_codex":[0.9981619,0.00006851118,0.0002860231,0.000409201,0.0006988383,0.0003755563],"domain_scores_gemma":[0.9982169,0.0004335512,0.0003456786,0.0003953151,0.0004253403,0.0001831845],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.001091338,0.0002490034,0.02381497,0.0002855778,0.0001955913,0.00004888147,0.0006726882,0.000004037435,0.9434183,0.00007654879,0.0000121123,0.03013096],"study_design_scores_gemma":[0.004946405,0.0001756352,0.2474379,0.0006159139,0.0003513141,0.0000501075,0.009413491,0.002563508,0.7183636,0.00001947914,0.01530694,0.0007556807],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.99201,0.0002835209,0.004718891,0.00009057437,0.000009772848,0.0002571881,0.00008127398,0.00003351253,0.002515266],"genre_scores_gemma":[0.9974375,0.0001088719,0.0003410845,0.000003180007,0.00002372364,0.000002352061,0.00007407326,0.00002545521,0.001983696],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.2250546,"threshold_uncertainty_score":0.9993101,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02069157889409641,"score_gpt":0.2400417784502283,"score_spread":0.2193501995561319,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}