{"id":"W2153191750","doi":"10.1002/chin.200645048","title":"Molecular Iodine in Isopropenyl Acetate (IPA): A Highly Efficient Catalyst for the Acetylation of Alcohols, Amines and Phenols under Solvent‐Free Conditions.","year":2006,"lang":"en","type":"article","venue":"ChemInform","topic":"Chemical Synthesis and Reactions","field":"Chemistry","cited_by":1,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Sherbrooke","funders":"","keywords":"Chemistry; Iodine; Catalysis; Organic chemistry; Acetylation; Phenols; Solvent; Biochemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00008220747,0.000144065,0.0001952386,0.0000355603,0.0000826742,0.0000283611,0.000174089,0.000102013,0.00008661404],"category_scores_gemma":[0.00007467416,0.0001017525,0.00009925515,0.0001265957,0.0001452653,0.00006018305,0.00007609024,0.00009024087,0.000002374809],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00007035076,"about_ca_system_score_gemma":0.00001937026,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001814098,"about_ca_topic_score_gemma":0.00004379979,"domain_scores_codex":[0.9991287,3.595559e-7,0.0003504638,0.0001731088,0.0001507409,0.0001966237],"domain_scores_gemma":[0.9992328,0.0001818811,0.0001617157,0.0003205351,0.00006602421,0.00003705176],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003111841,0.0001187012,0.00005717808,0.0001596574,0.00004286618,6.486126e-7,0.0001110038,0.0001707905,0.9933715,0.0007837926,0.001911886,0.003240852],"study_design_scores_gemma":[0.001050774,0.00000539918,0.0004613496,0.00006343043,0.0000687884,0.000006257811,0.0003047042,0.001375566,0.9926915,0.0004561477,0.003379632,0.0001364952],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9555115,0.0006629389,0.00005817383,0.0009452341,0.00003338168,0.0002933305,0.000158608,0.00003309708,0.04230374],"genre_scores_gemma":[0.9982165,0.000029401,0.00005817189,0.00002725574,0.00005797085,0.000127115,0.0002074372,0.00001524016,0.0012609],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.04270502,"threshold_uncertainty_score":0.4149347,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01228372301382055,"score_gpt":0.234010518003319,"score_spread":0.2217267949894985,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}