{"id":"W2153779963","doi":"10.1039/c0dt00141d","title":"Phosphido-bridged Ta/Rh bimetallic complex: synthesis, structure, and catalytic hydrosilylation of acetophenone","year":2010,"lang":"en","type":"article","venue":"Dalton Transactions","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":16,"is_retracted":false,"has_abstract":true,"ca_institutions":"Brock University","funders":"Royal Society","keywords":"Hydrosilylation; Deprotonation; Acetophenone; Bimetallic strip; Chemistry; Stereochemistry; Phosphine; Crystallography; Catalysis; Photochemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001162887,0.000260916,0.0001773647,0.0001274468,0.0001389925,0.0003074703,0.0004395504,0.0002362387,0.001561674],"category_scores_gemma":[0.0001802633,0.000142576,0.000107333,0.0002059736,0.0001727288,0.0002209425,0.0001799092,0.0002738718,0.0003927355],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005048136,"about_ca_system_score_gemma":0.0002881286,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001576312,"about_ca_topic_score_gemma":0.001691406,"domain_scores_codex":[0.9998895,0.00001085059,0.000007781127,0.00002359713,0.00003885588,0.00002945717],"domain_scores_gemma":[0.999931,0.000006861856,0.00001600379,0.00001355432,0.00001055502,0.0000219874],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001541936,0.00001949462,0.00008097948,0.00005149656,0.000006635318,0.00006410532,0.00002980159,0.0003075401,0.9969239,0.0002946185,0.00009736573,0.001970012],"study_design_scores_gemma":[0.00002083614,0.00008403358,0.0005286489,0.000001685861,0.000005201455,0.00009167491,0.000007632814,0.000815049,0.9967585,0.0000197811,0.001661866,0.000005134815],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9912101,0.0005680042,0.004139113,0.00007117296,0.0000150522,0.00005088253,0.0003021421,0.0001550691,0.003488545],"genre_scores_gemma":[0.993826,0.0001895948,0.002643644,0.0000154971,0.000003211044,0.00002041291,0.0002236479,0.0000264447,0.003051493],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001576312,"threshold_uncertainty_score":0.005224288,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01257452928790736,"score_gpt":0.2200309204769715,"score_spread":0.2074563911890642,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}