{"id":"W2153799385","doi":"10.1002/anie.200351876","title":"A Covalent Tetrathiafulvalene–Tetracyanoquinodimethane Diad: Extremely Low HOMO–LUMO Gap, Thermoexcited Electron Transfer, and High‐Quality Langmuir–Blodgett Films","year":2003,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Organic and Molecular Conductors Research","field":"Materials Science","cited_by":115,"is_retracted":false,"has_abstract":true,"ca_institutions":"Institut National de la Recherche Scientifique","funders":"","keywords":"Tetracyanoquinodimethane; Tetrathiafulvalene; HOMO/LUMO; Diad; Langmuir–Blodgett film; Covalent bond; Acceptor; Electron acceptor; Materials science; Chemistry; Photochemistry; Nanotechnology; Organic chemistry; Molecule; Monolayer; Physics; Copolymer; Condensed matter physics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.000721704,0.0002476772,0.0002485549,0.0001380026,0.0001269972,0.0001483191,0.0002800813,0.0001711823,0.003320851],"category_scores_gemma":[0.0003842442,0.0002332194,0.000100056,0.0001858376,0.000166919,0.0003665493,0.00004256445,0.0002645923,0.00009053292],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000145155,"about_ca_system_score_gemma":0.0001290301,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001989901,"about_ca_topic_score_gemma":0.00003908652,"domain_scores_codex":[0.9976704,0.000174514,0.0003855505,0.0005401465,0.0008082603,0.0004211988],"domain_scores_gemma":[0.9990677,0.0001519945,0.00008364828,0.000260382,0.0002676405,0.0001686597],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00007597061,0.0001694971,0.0002057111,0.00004707527,0.00004082744,0.0000256605,0.0001682032,0.000001775756,0.9949703,0.002235392,0.001742652,0.0003169865],"study_design_scores_gemma":[0.001067517,0.00009973869,0.002566841,0.00004662908,0.00002480608,0.00003851491,0.00006937933,0.000008854119,0.9912149,0.001279626,0.003309212,0.0002740359],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9895858,0.0007849103,0.003863541,0.0005516612,0.001094113,0.0002638045,0.0002480232,0.0001066409,0.003501529],"genre_scores_gemma":[0.9972932,0.0003746993,0.0003557138,0.0003073607,0.0003791749,0.0000535232,0.000319195,0.00003532422,0.0008818029],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00770743,"threshold_uncertainty_score":0.9975902,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02780198927678488,"score_gpt":0.2883322392545529,"score_spread":0.260530249977768,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}