{"id":"W2153799385","doi":"10.1002/anie.200351876","title":"A Covalent Tetrathiafulvalene–Tetracyanoquinodimethane Diad: Extremely Low HOMO–LUMO Gap, Thermoexcited Electron Transfer, and High‐Quality Langmuir–Blodgett Films","year":2003,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Organic and Molecular Conductors Research","field":"Materials Science","cited_by":115,"is_retracted":false,"has_abstract":true,"ca_institutions":"Institut National de la Recherche Scientifique","funders":"","keywords":"Tetracyanoquinodimethane; Tetrathiafulvalene; HOMO/LUMO; Diad; Langmuir–Blodgett film; Covalent bond; Acceptor; Electron acceptor; Materials science; Chemistry; Photochemistry; Nanotechnology; Organic chemistry; Molecule; Monolayer; Physics; Copolymer; Condensed matter physics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002109675,0.0003457028,0.0001951997,0.0002805876,0.0002745512,0.0003028131,0.0004079052,0.0003973904,0.0008845372],"category_scores_gemma":[0.0001123951,0.0002888784,0.0001239306,0.0001728215,0.0002027798,0.0002530104,0.000182099,0.0004839268,0.00032873],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003540046,"about_ca_system_score_gemma":0.0001193995,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003566842,"about_ca_topic_score_gemma":0.0007597411,"domain_scores_codex":[0.9998727,0.00001160463,0.00000731917,0.00004060151,0.00004092479,0.00002696721],"domain_scores_gemma":[0.9999062,0.00001385466,0.00002496118,0.00001298351,0.00001454582,0.00002750909],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001507688,0.00001540218,0.00007129608,0.00002966283,0.000003579793,0.00003662102,0.000009731825,0.00002300268,0.9990255,0.0001433964,0.00004782827,0.0005788715],"study_design_scores_gemma":[0.000009331493,0.0001400722,0.0006470684,0.000001686152,0.000007666373,0.0001424257,0.00000450866,0.0001576258,0.9968908,0.00002221279,0.001971474,0.000005016485],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9877957,0.002285597,0.006408018,0.0001730005,0.00006997903,0.00006357757,0.0003688808,0.0001745394,0.002660781],"genre_scores_gemma":[0.9863498,0.0008743874,0.007837328,0.00006846592,0.00001282243,0.00004218337,0.0004293895,0.00003778388,0.004347865],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0008845372,"threshold_uncertainty_score":0.002959073,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02780198927678488,"score_gpt":0.2883322392545529,"score_spread":0.260530249977768,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}