{"id":"W2154009506","doi":"10.1016/j.ejmech.2013.01.052","title":"Synthesis of decacationic [60]fullerene decaiodides giving photoinduced production of superoxide radicals and effective PDT-mediation on antimicrobial photoinactivation","year":2013,"lang":"en","type":"article","venue":"European Journal of Medicinal Chemistry","topic":"Fullerene Chemistry and Applications","field":"Chemistry","cited_by":48,"is_retracted":false,"has_abstract":false,"ca_institutions":"University of Toronto","funders":"National Institute of Allergy and Infectious Diseases; National Cancer Institute; National Institutes of Health","keywords":"Chemistry; Radical; Singlet oxygen; Photochemistry; Superoxide; Photoinduced electron transfer; Fullerene; Trifluoroacetic acid; Photosensitizer; Reactive oxygen species; Iodide; Electron transfer; Oxygen; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00007997017,0.0002431695,0.0001697294,0.0001565098,0.0001535038,0.0001835037,0.0001570103,0.0002976127,0.001300615],"category_scores_gemma":[0.0001171013,0.000126416,0.0001472539,0.0001664155,0.00008843699,0.0001622863,0.0001351103,0.0003573675,0.0002462798],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001674716,"about_ca_system_score_gemma":0.0001936318,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002344924,"about_ca_topic_score_gemma":0.000538724,"domain_scores_codex":[0.9999405,0.0000030033,0.000006578379,0.00001338182,0.0000159154,0.000020594],"domain_scores_gemma":[0.9999599,0.000005007859,0.00001083255,0.000006131053,0.000008190419,0.000009870104],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005144122,0.00001850593,0.00005070899,0.00005468578,0.000004191651,0.00007464281,0.00002287993,0.00009284825,0.9963787,0.0003292224,0.00007349904,0.0028487],"study_design_scores_gemma":[0.000007800203,0.00005310444,0.00029744,0.000002482894,0.000005047445,0.00005056028,0.000004966653,0.0001355216,0.9975049,0.00004459688,0.001890864,0.000002742098],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9859071,0.002003639,0.006075224,0.0001288175,0.0001093782,0.00007556831,0.0003925324,0.0001094855,0.005198152],"genre_scores_gemma":[0.9923199,0.0009294183,0.003460455,0.00004410352,0.00000778209,0.00004214861,0.0003173391,0.00001709026,0.002861748],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001300615,"threshold_uncertainty_score":0.00435096,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007670797439104578,"score_gpt":0.2116804266150049,"score_spread":0.2040096291759004,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}