{"id":"W2154103641","doi":"10.1002/anie.200461525","title":"Water‐Induced Rearrangement of a Platinacyclic Carbene Produces a Platinacyclic Carbaphosphazene with an Intraannular PtC Bond in a PtNPNPC Ring","year":2005,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Synthetic Organic Chemistry Methods","field":"Chemistry","cited_by":23,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"","keywords":"Carbene; Metallacycle; Chemistry; Ring (chemistry); Stereochemistry; Lewis acids and bases; Metal; Medicinal chemistry; Physics; Catalysis; Organic chemistry; X-ray crystallography","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0004223975,0.0003245273,0.000361187,0.000131688,0.00005359145,0.00004519111,0.0004100087,0.000188039,0.001117793],"category_scores_gemma":[0.0002367468,0.0002854504,0.00007865365,0.0001662748,0.00008427296,0.0004265183,0.00009955669,0.0003233719,0.000007343978],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004544319,"about_ca_system_score_gemma":0.00006686017,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003973938,"about_ca_topic_score_gemma":0.0002322285,"domain_scores_codex":[0.9977064,0.00002119888,0.0006339956,0.0006273363,0.0006126305,0.0003983979],"domain_scores_gemma":[0.9988242,0.0001109454,0.0002730874,0.0004780528,0.0001883836,0.0001252829],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002705225,0.0003510457,0.002458872,0.0001319851,0.00008559543,0.00002205243,0.001600441,0.00004727158,0.9918039,0.00003445098,0.00006435737,0.003129519],"study_design_scores_gemma":[0.001716429,0.00006542889,0.0009261623,0.0003542833,0.00004831338,0.00006757223,0.0005836292,0.000245568,0.9943461,0.0002437291,0.001062673,0.0003401228],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9863449,0.00007870506,0.0001148686,0.0008157666,0.0001850775,0.0001477487,0.000053657,0.00008797619,0.01217128],"genre_scores_gemma":[0.9938747,0.00002365604,0.003780152,0.0000455496,0.001451398,0.0001086383,0.0004049365,0.00005708331,0.0002538924],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01191739,"threshold_uncertainty_score":0.9999598,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01699928873951655,"score_gpt":0.2715184934239105,"score_spread":0.2545192046843939,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}