{"id":"W2154310542","doi":"10.1139/v08-150","title":"Probing solid iminobis(diorganophosphine chalcogenide) systems with multinuclear magnetic resonance","year":2008,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Advanced NMR Techniques and Applications","field":"Chemistry","cited_by":1,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Chemistry; Chalcogenide; Crystallography; Chemical shift; Chalcogen; Dihedral angle; Steric effects; Nuclear magnetic resonance spectroscopy; Solid-state nuclear magnetic resonance; Selenium; Stereochemistry; Nuclear magnetic resonance; Hydrogen bond; Molecule; Physical chemistry; Organic chemistry","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000116256,0.0001870208,0.0001638927,0.0001367923,0.0002026555,0.0002241869,0.0003003427,0.0002611721,0.001142023],"category_scores_gemma":[0.0002141998,0.0001167428,0.00004846534,0.0001805762,0.000333459,0.0003022265,0.0002612451,0.0003561457,0.0001461336],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002285489,"about_ca_system_score_gemma":0.0001306356,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000458614,"about_ca_topic_score_gemma":0.001087722,"domain_scores_codex":[0.9999092,0.00002028058,0.000003737985,0.0000193201,0.00003149776,0.0000160477],"domain_scores_gemma":[0.9999044,0.00003950832,0.00002107946,0.00001043976,0.00001407229,0.00001042816],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00008209286,0.00001204736,0.0002378124,0.0000718235,0.000004779107,0.00007151694,0.00006376427,0.0005947169,0.9975246,0.0002935768,0.00004706272,0.0009962789],"study_design_scores_gemma":[0.00002448772,0.0004527885,0.002730349,0.000008539749,0.00001358332,0.0001532649,0.0001794296,0.006577331,0.9879683,0.0002547623,0.001629101,0.000008047263],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9964336,0.0001652954,0.002089901,0.0000296565,0.000004410038,0.000008358644,0.00005105642,0.00001928911,0.001198388],"genre_scores_gemma":[0.9966751,0.0001388232,0.002313853,0.00001450388,0.000004095547,0.00001255436,0.00021101,0.000007974377,0.000622155],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001142023,"threshold_uncertainty_score":0.003820479,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01074286823935133,"score_gpt":0.2122529510506193,"score_spread":0.201510082811268,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}