{"id":"W2154406238","doi":"10.1562/2005-06-20-ra-581","title":"Bimolecular Hydrogen Abstraction from Phenols by Aromatic Ketone Triplets†","year":2005,"lang":"en","type":"article","venue":"Photochemistry and Photobiology","topic":"Photochemistry and Electron Transfer Studies","field":"Chemistry","cited_by":72,"is_retracted":false,"has_abstract":true,"ca_institutions":"McMaster University","funders":"","keywords":"Chemistry; Ketone; Photochemistry; Quenching (fluorescence); Hydrogen atom abstraction; Reaction rate constant; Triplet state; Thioxanthone; Hydrogen; Organic chemistry; Molecule; Kinetics; Fluorescence","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002796897,0.0003409511,0.0001349527,0.0001908181,0.0002476802,0.0001635612,0.0002296177,0.0002136635,0.002006224],"category_scores_gemma":[0.0003516678,0.00009603691,0.000156693,0.0001104624,0.0001804585,0.0003436292,0.0001663871,0.0002912648,0.0002602964],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004501958,"about_ca_system_score_gemma":0.0001636511,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001954194,"about_ca_topic_score_gemma":0.001781896,"domain_scores_codex":[0.9998821,0.00002378214,0.00000279039,0.0000270389,0.00002409474,0.00004018891],"domain_scores_gemma":[0.999828,0.00007439696,0.00003217457,0.000008720956,0.00003203768,0.0000246158],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0004505958,0.00003803424,0.004295312,0.000181045,0.00004153267,0.0001311949,0.00014537,0.001227556,0.9818665,0.0004293535,0.0002007061,0.01099272],"study_design_scores_gemma":[0.00001818357,0.0002876027,0.006013035,0.000005802934,0.00001924043,0.0001192327,0.00006270559,0.004689669,0.9879436,0.0001495964,0.0006798858,0.00001142448],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9962462,0.0006170327,0.002391608,0.0000271505,0.000008277017,0.000008029509,0.00008319923,0.00002000508,0.000598587],"genre_scores_gemma":[0.9983902,0.0002803993,0.0004625953,0.000007508183,0.000002924904,0.000004632779,0.000128044,0.000004135367,0.0007194303],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002006224,"threshold_uncertainty_score":0.006711543,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006958470577603914,"score_gpt":0.2198454807677074,"score_spread":0.2128870101901034,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}