{"id":"W2154436031","doi":"10.1021/jo030389j","title":"Total Synthesis of (±)-13-Methoxy-15-oxozoapatlin, a Rearranged Kaurane Diterpenoid","year":2004,"lang":"en","type":"article","venue":"The Journal of Organic Chemistry","topic":"Bioactive Natural Diterpenoids Research","field":"Biochemistry, Genetics and Molecular Biology","cited_by":17,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"","keywords":"Chemistry; Terpenoid; Bicyclic molecule; Octane; Stereochemistry; Diterpene; Total synthesis; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00007425949,0.0003128391,0.0002010655,0.0001794544,0.000131972,0.0001597842,0.0002445989,0.0001210753,0.002670262],"category_scores_gemma":[0.0000820952,0.00008841279,0.0001398465,0.0001878431,0.0001234111,0.0002374432,0.0002297635,0.0004145032,0.001105344],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001760715,"about_ca_system_score_gemma":0.0004094345,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003669067,"about_ca_topic_score_gemma":0.0006720959,"domain_scores_codex":[0.9999503,0.000005751736,0.000004207205,0.00001234252,0.00001201867,0.00001543456],"domain_scores_gemma":[0.9999563,0.000005079891,0.000008989055,0.000006086324,0.000007677058,0.00001598811],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00008102679,0.00002498474,0.00006648602,0.00008644296,0.000007023619,0.0001207709,0.00003349238,0.0002998468,0.9863572,0.0005429076,0.00007959141,0.01230024],"study_design_scores_gemma":[0.00002501209,0.0003823926,0.0004810239,0.000007147949,0.00001829996,0.0002867942,0.00002224471,0.0002073606,0.9836399,0.0001800594,0.01473845,0.00001137122],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9003737,0.005133698,0.0710718,0.0002500644,0.000173995,0.0004154729,0.002205301,0.0004131813,0.01996273],"genre_scores_gemma":[0.9553328,0.002818595,0.02913656,0.00006817694,0.00001787291,0.0001367505,0.00108102,0.00006492832,0.01134336],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002670262,"threshold_uncertainty_score":0.008932889,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007619764233806184,"score_gpt":0.2552088222925518,"score_spread":0.2475890580587456,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}