{"id":"W2155353850","doi":"10.1002/anie.200602569","title":"Total Synthesis of (+)‐Phyllantidine","year":2006,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Chemical synthesis and alkaloids","field":"Chemistry","cited_by":130,"is_retracted":false,"has_abstract":true,"ca_institutions":"Western University","funders":"","keywords":"Hydroxylamine; Cyclopropane; Natural product; Aldehyde; Content (measure theory); Total synthesis; Product (mathematics); Component (thermodynamics); Chemistry; Computer science; Natural (archaeology); World Wide Web; Information retrieval; Organic chemistry; Mathematics; History; Ring (chemistry); Physics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001050131,0.000323879,0.0002840201,0.0001794997,0.0002555005,0.0002549913,0.000397758,0.0002213012,0.009748635],"category_scores_gemma":[0.00009393435,0.0001951398,0.0002215469,0.0001987383,0.0001406409,0.0004247767,0.0004278934,0.0005572347,0.003583252],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002916527,"about_ca_system_score_gemma":0.0004699236,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004951606,"about_ca_topic_score_gemma":0.001124551,"domain_scores_codex":[0.9999294,0.000005991844,0.000005589718,0.00001927531,0.00001964453,0.00001998684],"domain_scores_gemma":[0.9999752,0.000002342382,0.000003016715,0.000006121221,0.000006169825,0.000007102413],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001852767,0.00006242514,0.0001362317,0.0008682405,0.00005038573,0.0004773169,0.0002225216,0.001062752,0.8995208,0.01139663,0.005760323,0.08025711],"study_design_scores_gemma":[0.0000927355,0.0007942939,0.0006710713,0.0000644988,0.00006123588,0.000843984,0.00005887795,0.0008614783,0.8454656,0.002347667,0.1487003,0.00003835005],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.5882772,0.01570812,0.1011391,0.001739967,0.001446332,0.0005184078,0.00868335,0.00372428,0.2787634],"genre_scores_gemma":[0.8965142,0.01008612,0.02772264,0.000360547,0.0000810998,0.0002674516,0.002354276,0.000231776,0.06238191],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.009748635,"threshold_uncertainty_score":0.03261244,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007081387982704915,"score_gpt":0.2175159622856259,"score_spread":0.210434574302921,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}