{"id":"W2155409278","doi":"10.1002/anie.200502788","title":"Discovery of a Pseudo β Barrel: Synthesis and Formation by Tiling of Ferrocene Cyclopeptides","year":2005,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Ferrocene Chemistry and Applications","field":"Chemistry","cited_by":48,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Saskatchewan","funders":"","keywords":"Barrel (horology); Ferrocene; Crystallography; Chemistry; Stereochemistry; Combinatorial chemistry; Materials science; Electrochemistry; Composite material; Electrode","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00006979355,0.0001186124,0.0001475169,0.00003623454,0.00004097375,0.0000216366,0.0001530592,0.0000941574,0.0002571344],"category_scores_gemma":[0.0001329433,0.0001236051,0.00006401666,0.00006064017,0.00008134683,0.000578372,0.00004292758,0.00008461112,0.000002794129],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00006510467,"about_ca_system_score_gemma":0.00001895331,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001685611,"about_ca_topic_score_gemma":0.000003403524,"domain_scores_codex":[0.9991372,0.000002920995,0.0003528763,0.0001772418,0.0002298639,0.00009994982],"domain_scores_gemma":[0.9993243,0.0001162822,0.0002489222,0.000133268,0.0001409283,0.00003632291],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003758751,0.0001057626,0.0002502758,0.0001714353,0.00003521828,1.912089e-7,0.0001055985,0.00002136446,0.9933782,0.0001437179,0.004120268,0.001630448],"study_design_scores_gemma":[0.0002471374,0.000004235598,0.0001024389,0.0001862906,0.00002993515,0.00001164566,0.0002086685,0.0004744092,0.995306,0.0002547619,0.003063761,0.0001106939],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9786298,0.0001855859,0.002028035,0.0006958272,0.00004737431,0.00003999176,0.0005614628,0.00003627521,0.01777566],"genre_scores_gemma":[0.9975984,0.0003091551,0.0005636392,0.00003279356,0.0003714264,0.00004555234,0.0005627402,0.0000127455,0.0005036249],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01896853,"threshold_uncertainty_score":0.5040471,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01019420402561982,"score_gpt":0.2403072773172918,"score_spread":0.230113073291672,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}