{"id":"W2155477670","doi":"10.1002/anie.200803344","title":"Stable 5‐Substituted Cyclopentadienes for the Diels–Alder Cycloaddition and their Application to the Synthesis of Palau'amine","year":2008,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Asymmetric Synthesis and Catalysis","field":"Chemistry","cited_by":66,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University","funders":"","keywords":"Amine gas treating; Cycloaddition; Hydride; Reactivity (psychology); Chemistry; Ring (chemistry); Computer science; Organic chemistry; Combinatorial chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002919877,0.0004311518,0.0001427465,0.0002257975,0.0002171215,0.0003221729,0.0002579705,0.0003551185,0.003796504],"category_scores_gemma":[0.0001676141,0.000294414,0.0002136772,0.0002133997,0.0002761758,0.0005479922,0.0003241125,0.0006031084,0.000870192],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003794866,"about_ca_system_score_gemma":0.0003603047,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004156946,"about_ca_topic_score_gemma":0.001069556,"domain_scores_codex":[0.9998907,0.00002064924,0.00001030576,0.00001831777,0.00003296628,0.00002708905],"domain_scores_gemma":[0.9999415,0.00001256663,0.00001894236,0.000008903136,0.000006872761,0.00001121287],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001802933,0.00006043592,0.0000860605,0.0002388853,0.00001166066,0.0003477604,0.0001429417,0.0005118412,0.9799621,0.005586449,0.0003263631,0.01254522],"study_design_scores_gemma":[0.00006880975,0.0005675949,0.0006717787,0.00001954785,0.00001247712,0.0003706859,0.00003680072,0.001111583,0.982754,0.0005379664,0.01382137,0.00002741367],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8854252,0.009299373,0.05722023,0.0005404466,0.0002736117,0.0003354413,0.0005791704,0.0003657599,0.04596092],"genre_scores_gemma":[0.9722601,0.004314953,0.01447877,0.00007072728,0.00002133219,0.0001146851,0.0003057107,0.00003572824,0.008397918],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003796504,"threshold_uncertainty_score":0.01270062,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01371730206806004,"score_gpt":0.2282702277556936,"score_spread":0.2145529256876336,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}