{"id":"W2155903837","doi":"10.1039/b914757h","title":"Construction of protected hydroxylated pyrrolidines using nitrogen-centered radical cyclizations","year":2009,"lang":"en","type":"article","venue":"Chemical Communications","topic":"Carbohydrate Chemistry and Synthesis","field":"Chemistry","cited_by":19,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"","keywords":"Chemistry; Silylation; Enol; Hydroxymethyl; Nitrogen; Ribitol; Organic chemistry; Catalysis; Enzyme","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003181087,0.0005642879,0.0003123965,0.0002557873,0.0001549203,0.000348339,0.0004336514,0.0003083498,0.001778945],"category_scores_gemma":[0.0002979156,0.0002191094,0.0004161119,0.0002035721,0.0002787423,0.0003764492,0.0003103491,0.000763149,0.0006916483],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002186282,"about_ca_system_score_gemma":0.0002356237,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001667057,"about_ca_topic_score_gemma":0.0003272113,"domain_scores_codex":[0.9998069,0.00002847167,0.00001952272,0.00004213735,0.00004068539,0.00006223519],"domain_scores_gemma":[0.9997428,0.00004092454,0.00007435226,0.00004164607,0.00003827392,0.00006204193],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00008130333,0.00003005302,0.00005030563,0.00006409182,0.000007007512,0.0001931007,0.00004680418,0.0002208417,0.9953527,0.0006636313,0.00004929279,0.003240799],"study_design_scores_gemma":[0.00001377265,0.0002146071,0.0002105175,0.000002875932,0.000009693227,0.00009260591,0.00001041118,0.0002610669,0.9968327,0.00005516226,0.002288686,0.000007899122],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9606891,0.001787744,0.03080562,0.0001676355,0.0002632477,0.0001691592,0.000486423,0.000374556,0.005256443],"genre_scores_gemma":[0.9758195,0.001196284,0.01808066,0.00006926138,0.00003994783,0.00006780984,0.0005005859,0.00007216351,0.004153807],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001778945,"threshold_uncertainty_score":0.005951107,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0424868675042397,"score_gpt":0.2769842351207314,"score_spread":0.2344973676164917,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}