{"id":"W2156284977","doi":"10.1002/anie.201400807","title":"Intermolecular Domino Reaction of Two Aryl Iodides Involving Two CH Functionalizations","year":2014,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Catalytic C–H Functionalization Methods","field":"Chemistry","cited_by":113,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Intermolecular force; Aryl; Domino; Palladium; Ring (chemistry); Chemistry; Coupling reaction; Coupling (piping); Catalysis; Combinatorial chemistry; Computational chemistry; Organic chemistry; Materials science; Molecule","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003555033,0.0008905423,0.0003823847,0.0004341088,0.0004119411,0.0004469342,0.0009653461,0.0005343395,0.002828406],"category_scores_gemma":[0.0002154363,0.0003292428,0.0003219536,0.0004229163,0.0005281345,0.0006569386,0.00131907,0.001004187,0.0008382237],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004916499,"about_ca_system_score_gemma":0.0005043675,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0008103711,"about_ca_topic_score_gemma":0.00169105,"domain_scores_codex":[0.9996433,0.00003129491,0.00001904213,0.0000725641,0.00006126006,0.0001725235],"domain_scores_gemma":[0.9998943,0.00002102747,0.00001899574,0.00002121277,0.00001256028,0.00003197868],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001949088,0.0001421374,0.0002622897,0.0003642697,0.00003959155,0.00101895,0.0003300325,0.0006905452,0.9745055,0.00859761,0.0007877002,0.01306638],"study_design_scores_gemma":[0.00004596508,0.0003933393,0.0005711124,0.00001409137,0.00002702854,0.000440488,0.0000448271,0.001273639,0.9870089,0.0003336814,0.009809524,0.0000373526],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9227998,0.003548432,0.02383422,0.000345115,0.0002860736,0.0001817413,0.0003379128,0.0005363214,0.04813044],"genre_scores_gemma":[0.9892436,0.001014541,0.003486553,0.00006043146,0.00002201364,0.0000504866,0.0001230613,0.00002664402,0.005972554],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002828406,"threshold_uncertainty_score":0.009461999,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02158637134698463,"score_gpt":0.2959698621500363,"score_spread":0.2743834908030517,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}