{"id":"W2157153108","doi":"10.1142/s1088424612501271","title":"Shape-persistent poly-porphyrins assembled by a central truxene: synthesis, structure, and singlet energy transfer behaviors","year":2012,"lang":"en","type":"article","venue":"Journal of Porphyrins and Phthalocyanines","topic":"Porphyrin and Phthalocyanine Chemistry","field":"Materials Science","cited_by":19,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Sherbrooke","funders":"","keywords":"Chemistry; Porphyrin; Acceptor; Singlet state; Photochemistry; Steric effects; Crystallography; Energy transfer; Fluorescence; Förster resonance energy transfer; Stereochemistry; Chemical physics; Excited state","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0004287639,0.00052883,0.000788365,0.0001536545,0.0002360146,0.0001942057,0.0003671639,0.0002551899,0.001125759],"category_scores_gemma":[0.00005861989,0.0004278484,0.0002938675,0.0001823878,0.0001864879,0.0007074628,0.00009077659,0.0003137824,0.000002749972],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00007354393,"about_ca_system_score_gemma":0.00009814589,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001684869,"about_ca_topic_score_gemma":0.000009722182,"domain_scores_codex":[0.9971473,0.000124117,0.0008764957,0.0003814741,0.0005751465,0.0008955238],"domain_scores_gemma":[0.9981408,0.0001456113,0.0003925304,0.0002822203,0.0001518636,0.0008869954],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001773075,0.0003734186,0.03010971,0.00009451021,0.0001013607,0.00007226411,0.0004176,0.000002790642,0.9653476,0.0002557053,0.001100578,0.001947183],"study_design_scores_gemma":[0.001400863,0.0003931844,0.02455537,0.0001714042,0.0004601127,0.006010211,0.0003817197,0.00004035141,0.9586505,0.00007389038,0.007123579,0.0007387573],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9886422,0.009535197,0.00009265298,0.0001860412,0.0007030524,0.00008532227,0.0002457936,0.00003252001,0.0004772468],"genre_scores_gemma":[0.9976739,0.0005432867,0.0005857544,0.0001389154,0.0008121502,0.000006058139,0.00001521298,0.00005969962,0.0001650171],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.009031732,"threshold_uncertainty_score":0.9998173,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01075759959122672,"score_gpt":0.2216234979559937,"score_spread":0.210865898364767,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}