{"id":"W2157624939","doi":"10.1021/ol050094n","title":"Transition Metal-Catalyzed Synthesis and Reactivity of <i>N</i>-Alkenyl Aziridines","year":2005,"lang":"en","type":"article","venue":"Organic Letters","topic":"Catalytic C–H Functionalization Methods","field":"Chemistry","cited_by":51,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"Natural Sciences and Engineering Research Council of Canada; Amgen","keywords":"Chemistry; Reactivity (psychology); Halide; Catalysis; Palladium; Transition metal; Organic chemistry; Combinatorial chemistry; Copper; Medicinal chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002318391,0.0003286447,0.0002141369,0.0001489279,0.0001624092,0.0002688904,0.0004650962,0.0003108208,0.000766399],"category_scores_gemma":[0.0002211248,0.0001527568,0.0001696757,0.000173306,0.0001988571,0.0003116974,0.0001799369,0.0003576015,0.0002700862],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003492394,"about_ca_system_score_gemma":0.0001423516,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004081935,"about_ca_topic_score_gemma":0.0007971472,"domain_scores_codex":[0.9998432,0.00002644181,0.00001767762,0.00004072837,0.00004145615,0.0000305055],"domain_scores_gemma":[0.9998993,0.00001957652,0.00003577548,0.00001362713,0.00001398541,0.00001778603],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00009791437,0.00002089385,0.00008483136,0.00008173619,0.00001028841,0.00009444779,0.00003108732,0.0003288319,0.9956213,0.0006925816,0.00006527226,0.002870769],"study_design_scores_gemma":[0.00001061054,0.0001571653,0.00029493,0.000002971407,0.000007459824,0.0001308348,0.000006156236,0.00050285,0.9973105,0.00005960314,0.001512053,0.00000485633],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9747368,0.003658225,0.01082421,0.00006464026,0.00004718096,0.00007392739,0.0003391439,0.00009258222,0.01016339],"genre_scores_gemma":[0.9892285,0.001771926,0.006773204,0.00002597608,0.00001087835,0.00002584295,0.0002468301,0.0000172345,0.001899625],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.000766399,"threshold_uncertainty_score":0.002563834,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01320616182707719,"score_gpt":0.2334835492515176,"score_spread":0.2202773874244404,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}