{"id":"W2157631697","doi":"10.1016/j.jfluchem.2005.07.009","title":"A laboratory-scale synthesis of high-purity AsF5 by direct fluorination of AsF3","year":2005,"lang":"en","type":"article","venue":"Journal of Fluorine Chemistry","topic":"Inorganic Fluorides and Related Compounds","field":"Chemistry","cited_by":19,"is_retracted":false,"has_abstract":false,"ca_institutions":"McMaster University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Scale (ratio); Environmental chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003907718,0.0003472909,0.000344068,0.0002286339,0.0004164709,0.0002898973,0.0004785314,0.0003491376,0.001332255],"category_scores_gemma":[0.000156809,0.0001463108,0.0003203569,0.0001692969,0.0002135188,0.0002599831,0.0001868567,0.00039994,0.0004124937],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004324457,"about_ca_system_score_gemma":0.000458307,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001508498,"about_ca_topic_score_gemma":0.002957779,"domain_scores_codex":[0.9998486,0.00001999948,0.00001012922,0.00003159434,0.00005927794,0.00003044635],"domain_scores_gemma":[0.999944,0.000009276619,0.00001046751,0.00001319042,0.00001157601,0.00001146583],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00007528009,0.00003387475,0.0001361733,0.00009821279,0.00001055303,0.00005911637,0.00002982556,0.0001498349,0.990628,0.0006345335,0.0003121696,0.007832533],"study_design_scores_gemma":[0.00001414393,0.0001874595,0.0004296681,0.000002975221,0.0000090881,0.00007867972,0.00001386775,0.0006500007,0.9948679,0.00006982413,0.00367018,0.000006195075],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9412899,0.003177114,0.04351369,0.0003244281,0.0002212429,0.0002063674,0.001006047,0.0007668035,0.009494408],"genre_scores_gemma":[0.9802504,0.0005767875,0.01658583,0.00002160432,0.00001534014,0.00003262719,0.0004109695,0.00002759222,0.002078975],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001508498,"threshold_uncertainty_score":0.004456818,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.002714542677345478,"score_gpt":0.1932208445111799,"score_spread":0.1905063018338344,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}