{"id":"W2157654470","doi":"10.1002/chem.201501904","title":"Activation of Carbon Dioxide by Silyl Triflate‐Based Frustrated Lewis Pairs","year":2015,"lang":"en","type":"article","venue":"Chemistry - A European Journal","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":66,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Silylation; Trifluoromethanesulfonate; Chemistry; Phosphine; Alkyl; Lewis acids and bases; Medicinal chemistry; Carbon dioxide; Molecule; Carbon fibers; Frustrated Lewis pair; Organic chemistry; Catalysis; Materials science","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001387827,0.0003646066,0.000226904,0.0001868691,0.000225638,0.0002365983,0.000331074,0.0003248627,0.001720316],"category_scores_gemma":[0.0002054378,0.0001127681,0.0001762174,0.0001336046,0.000282837,0.0002790082,0.0003266796,0.0002132762,0.0002905603],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002506117,"about_ca_system_score_gemma":0.000184066,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006323605,"about_ca_topic_score_gemma":0.001263815,"domain_scores_codex":[0.9998546,0.00002243544,0.000005917682,0.00002239104,0.00003172503,0.00006293909],"domain_scores_gemma":[0.9999051,0.00002817146,0.00002414562,0.0000136035,0.00001186214,0.00001703229],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002414608,0.00001975345,0.0001678886,0.0001058106,0.00001499963,0.0001515257,0.00005228299,0.0004221685,0.9956719,0.0008965721,0.0002014178,0.002054402],"study_design_scores_gemma":[0.00003583746,0.0002144798,0.0005434131,0.000002912559,0.000006216131,0.00018135,0.0000200521,0.001888764,0.9953307,0.000122531,0.001641655,0.00001213837],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.993094,0.0004786684,0.001724097,0.00005111044,0.00001682767,0.0000210877,0.0001000045,0.00006275903,0.004451584],"genre_scores_gemma":[0.9980799,0.0001868555,0.0007547586,0.00001634015,0.000005677769,0.00001219567,0.0001263562,0.00001243756,0.0008054364],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001720316,"threshold_uncertainty_score":0.005755007,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02220400083971595,"score_gpt":0.2232128337707247,"score_spread":0.2010088329310087,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}